1284222-79-2Relevant academic research and scientific papers
Broadly Applicable Stereoselective Syntheses of Serrulatane, Amphilectane Diterpenes, and Their Diastereoisomeric Congeners Using Asymmetric Hydrovinylation for Absolute Stereochemical Control
Tenneti, Srinivasarao,Biswas, Souvagya,Cox, Glen Adam,Mans, Daniel J.,Lim, Hwan Jung,RajanBabu
, p. 9868 - 9881 (2018/07/25)
A stereogenic center, placed at an exocyclic location next to a chiral carbon in a ring to which it is attached, is a ubiquitous structural motif seen in many bioactive natural products, including di- and triterpenes and steroids. Installation of these ce
Ethylene in organic synthesis. repetitive hydrovinylation of alkenes for highly enantioselective syntheses of pseudopterosins
Mans, Daniel J.,Cox, G. Adam,Rajanbabu
, p. 5776 - 5779 (2011/05/30)
In this report we highlight the significant potential of ethylene as a reagent for the introduction of a vinyl group with excellent stereoselectivity at three different stages in the synthesis of a broad class of natural products, best exemplified by synt
