214282-99-2Relevant academic research and scientific papers
Broadly Applicable Stereoselective Syntheses of Serrulatane, Amphilectane Diterpenes, and Their Diastereoisomeric Congeners Using Asymmetric Hydrovinylation for Absolute Stereochemical Control
Tenneti, Srinivasarao,Biswas, Souvagya,Cox, Glen Adam,Mans, Daniel J.,Lim, Hwan Jung,RajanBabu
supporting information, p. 9868 - 9881 (2018/07/25)
A stereogenic center, placed at an exocyclic location next to a chiral carbon in a ring to which it is attached, is a ubiquitous structural motif seen in many bioactive natural products, including di- and triterpenes and steroids. Installation of these ce
Enantiospecific syntheses of pseudopterosin aglycones - Part 1. Synthesis of the putative aglycone of pseudopterosin G-J via an A→AB→ABC annulation strategy
Chow, Robert,Kocienski, Philip J.,Kuhl, Alexander,LeBrazidec, Jean-Yves,Muir, Kenneth,Fish, Paul
, p. 2344 - 2355 (2007/10/03)
The putative aglycone of pseudopterosin G-J and its enantiomer were synthesised enantiospecifically from 2,3-dimethoxytoluene and η3-allyl cationic complexes of molybdenum and iron respectively. The A→AB→ABC annulation strategy entailed the use of allyl cations or their equivalents for the creation of the three benzylic stereogenic centres. The X-ray structure of tetrahydronaphthalene (-)-41a was determined.
