128530-69-8

Upstream product

• 100-39-0 benzyl bromide 
• 128503-17-3 (-)-(1R,2S,4S)-6-bromo-7-oxabicyclo<2.2.1>hept-5-en-2-endo-ol 
• 128503-17-3 (+/-)-(1RS,2SR,4SR)-6-bromo-7-oxabicyclo<2.2.1>hept-5-en-2-endo-ol 
• 95530-78-2 7-oxabicyclo[2.2.1]hept-5-en-2-one 
• 128503-15-1 (+/-)-(1RS,4SR,5SR,6SR)-5-exo-benzeneselenyl-6-endo-bromo-7-oxabicyclo<2.2.1>heptan-2-one 
• 146352-77-4 (1RS,2SR,4SR)-6-bromo-7-oxabicyclo<2.2.1>hept-5-en-2-endo-yl trifluoromethanesulfonate 
• 100-51-6 benzyl alcohol 

Downstream Products

• 128503-18-4 (-)-(1R,3S,4S,6S)-6-endo-benzyloxy-3-exo-hydroxy-7-oxabicyclo<2.2.1>heptan-2-one 
• 128503-19-5 (-)-(1R,3S,4S,6S)-6-endo-benzyloxy-2-oxo-7-oxabicyclo<2.2.1>hept-3-exo-yl acetate 
• 128503-18-4 (+/-)-(1RS,3SR,4SR,6SR)-6-endo-benzyloxy-3-exo-hydroxy-7-oxabicyclo<2.2.1>heptan-2-one 
• 128503-19-5 (+/-)-(1RS,3SR,4SR,6SR)-6-endo-benzyloxy-2-oxo-7-oxabicyclo<2.2.1>hept-3-exo-yl acetate 

Relevant academic research and scientific papers

Total asymmetric syntheses of d-lividosamine and 2-acetamido-2,3-dideoxy-d-arabino-hexose derivatives

The "naked sugar" (+)-(1R, 4R)-7-oxabicyclo[2.2.1]hept-5-en-one((+)-2) has been converted to D-lividosamine ((+)-1: 3-deoxy-D-glucosamine) and derivatives via (+)-2-chloro-2,3-dideoxy-5,6-O-isopropyridene-D-arabino-hexono-1,4-lactone ((+)-33) and (+)-2-az

TOTAL ASYMMETRIC SYNTHESES OF 3- AND 4-DEOXY-HEXOSES AND DERIVATIVES.

(1S,4S)-7-Oxabicyclohept-5-en-2-one ((-)-5, a "naked sugar") has been converted to (-)-(1R,4S,6S)-6-endo-benzyloxy-2-bromo-7-oxabicyclohept-2-ene ((-)-12) in a highly stereoselective fashion.Double hydroxylation of the C=C double bond of (-)

THE ELECTRON-RELEASING HOMOCONJUGATED CARBONYL GROUP. APPLICATION TO THE TOTAL SYNTHESES OF 3-DEOXY-,4-DEOXY-HEXOSE,LIVIDOSAMINE AND DERIVATIVES

The regioselective electrophilic addition of benzeneselenyl bromide to (-)-(1S,4S)-7-oxabicyclo-hept-5-en-2-one were exploited to develop efficient syntheses of methyl 3-deoxy-α-D-arabino-hexofuranoside and 4-deoxy-D-lyxo-hexopyranose.Similarly, D-