128550-75-4Relevant academic research and scientific papers
Substrate Leaving Group Control of the Enantioselectivity in the Palladium-Catalyzed Asymmetric Allylic Substitution of 4-Alkyl-1-vinylcyclohexyl Derivatives
Fiaud, Jean-Claude,Legros, Jean-Yves
, p. 4840 - 4846 (1990)
The strong influence of the nature of the leaving group in allylic derivatives in their enantioselective Pd-catalyzed substitution by nucleophile is reported.Analysis of the stereochemical course of the Pd-catalyzed substitution of achiral trans-4-tert-bu
