Substrate Leaving Group Control of the Enantioselectivity in the Palladium-Catalyzed Asymmetric Allylic Substitution of 4-Alkyl-1-vinylcyclohexyl Derivatives

DOI: 10.1021/jo00303a016

Source and publish data:

Journal of Organic Chemistry p. 4840 - 4846 (1990)

Update date:2022-08-04

Topics:

Authors:

Fiaud, Jean-Claude

Legros, Jean-Yves

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00303a016

The strong influence of the nature of the leaving group in allylic derivatives in their enantioselective Pd-catalyzed substitution by nucleophile is reported.Analysis of the stereochemical course of the Pd-catalyzed substitution of achiral trans-4-tert-bu

Full text of DOI:10.1021/jo00303a016

Products guided by the article

Product name:trans-1-Ethenyl-4-(1,1-dimethylethyl)cyclohexanol methyl carbonate

Cas No:128550-75-4

R&D Labs maybe for 128550-75-4

Shantou Baokang Pharmaceutical Co., Ltd.

Contact:+86-754-88873487

Address:5/F B Block Huangshan Bldg Huangshan Rd Shantou
shijiazhuang shuanglian chemical industry co.,ltd

Contact:0311-82190302

Address:Luquan Intersection , Shijiazhuang--Taiyuan Expressway，Shijiazhuang City
Afine Chemicals Limited

website:http://www.afinechem.com

Contact:+86-571-85134551

Address:No. 206 Zhen Hua Road, Hangzhou 310030, Zhejiang, China
Puyang Willing Chemicals Co.,Ltd.

Contact:86-393-4840366

Address:Puyang Henan China
Rudong Zhenfeng Yiyang Chemical Co., Ltd.

Contact:0513-84573047

Address:South Fengli Town, Rudong County, Jiangsu Province, China

Relevant to this article

Rh-Catalyzed Asymmetric Hydrogenation of β-Substituted-β-thio-α,β-unsaturated Esters: Expeditious Access to Chiral Organic Sulfides

Doi:10.1021/acs.orglett.8b02339
(2018)
SYNTHESIS OF (+/-)-3-AMINO-2,4-DIHYDROXY-6-HYDROXYMETHYL-8-OXABICYCLO<3.2.1>OCTANE DERIVATIVES, AND THEIR ANHYDRO-RING-MIGRATION WITH HYDROGEN BROMIDE-ACETIC ACID

Doi:10.1016/0008-6215(89)85011-6
(1989)
4-NITROBENZYL GROUP FOR PROTECTION OF HYDROXYL FUNCTIONS

Doi:10.1016/S0040-4039(00)94562-3
(1990)
Photocontrolled reversible room temperature phosphorescence (RTP) encoding β-cyclodextrin pseudorotaxane

Doi:10.1039/c0cc05488g
(2011)
Organocatalyzed reactions involving 3-formylchromones and acetylenedicarboxylates: Efficient synthesis of functionalized benzophenones and polysubstituted xanthones

Doi:10.1055/s-0030-1258969
(2011)
Iodocyclization of hydroxylamine derivatives based on the control of oxidative aromatization leading to 2,5-dihydroisoxazoles and isoxazoles

Doi:10.1021/jo200407b
(2011)

Article Doi