Substrate Leaving Group Control of the Enantioselectivity in the Palladium-Catalyzed Asymmetric Allylic Substitution of 4-Alkyl-1-vinylcyclohexyl Derivatives

DOI: 10.1021/jo00303a016

Source and publish data:

Journal of Organic Chemistry p. 4840 - 4846 (1990)

Update date:2022-08-04

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Authors:

Fiaud, Jean-Claude

Legros, Jean-Yves

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Article abstract of DOI:10.1021/jo00303a016

The strong influence of the nature of the leaving group in allylic derivatives in their enantioselective Pd-catalyzed substitution by nucleophile is reported.Analysis of the stereochemical course of the Pd-catalyzed substitution of achiral trans-4-tert-bu

Full text of DOI:10.1021/jo00303a016

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