1285718-94-6Relevant articles and documents
Enantioselective synthesis of heteroaromatic epoxyketones under phase-transfer catalysis using D-glucose- and D-mannose-based crown ethers
Rapi, Zsolt,Szabo, Tamas,Keglevich, Gyoergy,Szxoellosy, Aron,Drahos, Laszlo,Bako, Peter
, p. 1189 - 1196 (2011)
Heteroaromatic epoxyketones have been synthesized in an asymmetric Darzens condensation of 2-chloroacetylfuran or 2- and 3-chloroacetylthiophene with aromatic aldehydes and in the enantioselective epoxidation of α,β-enones with an N-methylpyrrole unit, in
Asymmetric C-C bond formation via Darzens condensation and Michael addition using monosaccharide-based chiral crown ethers
Bakó, Péter,Rapi, Zsolt,Keglevich, Gy?rgy,Szabó, Tamás,Sóti, Péter L.,Vígh, Tamás,Grn, Alajos,Holczbauer, Tamás
experimental part, p. 1473 - 1476 (2011/06/10)
Liquid-liquid phase asymmetric Darzens condensations were promoted by d-glucose- and d-mannose-based crown ethers. The corresponding aromatic and heteroaromatic α,β-epoxyketones were obtained with moderate to high enantioselectivities (up to 96%) as well