128573-16-0

Upstream product

• 5707-04-0 Phenylselenyl chloride 
• 88708-22-9 (+)-(1R,4R)-7-oxabicyclo<2.2.1>-hept-5-en-2-one 

Downstream Products

• 128530-72-3 (-)-(1S,4R,5R,6R)-5-exo-benzeneselenyl-2-<(tert-butyl)dimethylsilyloxy>-6-endo-chloro-7-oxabicyclo<2.2.1>hept-2-ene 
• 170873-06-0 (1R,2S,3R,4S)-3-endo-Chloro-5-oxo-2-endo-(phenylseleno)-7-oxabicyclo<2.2.1>hept-2-exo-yl acetate 
• 170873-07-1 (1R,2S,3R,4S)-3-endo-Chloro-5-oxo-2-endo-(phenylseleno)-7-oxabicyclo<2.2.1>hept-2-exo-yl 3'-chlorobenzoate 
• 263405-23-8 (-)-(1S,3S,4R,5R,6R)-6-endo-chloro-3-exo-{(R)-hydroxy[(3aS,4aS,7aS,7bR)-3a,4a,7a,7b-tetrahydro-6,6-dimethyl[1,3]dioxolo[4,5]furo[2,3-d]isoxazol-3-yl]methyl}-5-exo-(phenylseleno)-7-oxabicyclo[2.2.1]heptan-2-one 
• 248243-20-1 (+)-(1S,3S,4R,5R,6R)-6-endo-chloro-3-exo-{(S)-hydroxy[(3aR,4aR,7aR,7bS)-3a,4a,7a,7b-tetrahydro-6,6-dimethyl[1,3]dioxolo[4,5]furo[2,3-d]isoxazol-3-yl]methyl}-5-exo-(phenylseleno)-7-oxabicyclo[2.2.1]heptan-2-one 
• 263405-21-6 (+)-(1S,3S,4R,5R,6R)-6-endo-chloro-3-exo-{(R)-hydroxy[(3aR,4aR,7aR,7bS)-3a,4a,7a,7b-tetrahydro-6,6-dimethyl[1,3]dioxolo[4,5]furo[2,3-d]isoxazol-3-yl]methyl}-5-exo-(phenylseleno)-7-oxabicyclo[2.2.1]heptan-2-one 
• 263405-31-8 (-)-(1S,2R,3S,4R,5R,6R)-3-exo-{(S)-[(tert-butyl)dimethylsilyloxy][(3aS,4aS,7aS,7bR)-3a,4a,7a,7b-tetrahydro-6,6-dimethyl[1,3]dioxolo[4,5]furo[2,3-d]isoxazol-3-yl]methyl}-6-endo-chloro-5-exo-(phenylseleno)-7-oxabicyclo[2.2.1]heptan-2-endo-ol 
• 263405-32-9 (-)-(1S,2R,3S,4R,5R,6R)-3-exo-{(R)-[(tert-butyl)dimethylsilyloxy][(3aS,4aS,7aS,7bR)-3a,4a,7a,7b-tetrahydro-6,6-dimethyl[1,3]dioxolo[4,5]furo[2,3-d]isoxazol-3-yl]methyl}-6-endo-chloro-5-exo-(phenylseleno)-7-oxabicyclo[2.2.1]heptan-2-endo-ol 
• 263405-28-3 (-)-(1S,2R,3R,4R,5R,6R)-6-endo-chloro-3-exo-{(S)-hydroxy[(3aR,4aR,7aR,7bS)-3a,4a,7a,7b-tetrahydro-6,6-dimethyl[1,3]dioxolo[4,5]furo[2,3-d]isoxazol-3-yl]methyl}-5-exo-(phenylseleno)-7-oxabicyclo[2.2.1]heptan-2-endo-ol 
• 248243-21-2 (+)-(1S,3S,4R,5R,6R)-6-endo-chloro-3-exo-{(S)-[(tert-butyl)dimethylsilyloxy][(3aR,4aR,7aR,7bS)-3a,4a,7a,7b-tetrahydro-6,6-dimethyl[1,3]dioxolo[4,5]furo[2,3-d]isoxazol-3-yl]methyl}-5-exo-(phenylseleno)-7-oxabicyclo[2.2.1]heptan-2-one 
• 248243-22-3 (-)-(1S,2R,3S,4R,5R,6R)-3-exo-{(S)-[(tert-butyl)dimethylsilyloxy][(3aR,4aR,7aR,7bS)-3a,4a,7a,7b-tetrahydro-6,6-dimethyl[1,3]dioxolo[4,5]furo[2,3-d]isoxazol-3-yl]methyl}-6-endo-chloro-5-exo-(phenylseleno)-7-oxabicyclo[2.2.1]heptan-2-endo-ol 
• 248243-24-5 (+)-(1S,2R,3R,4R,5R,6R)-3-exo-{(S)-[(tert-butyl)dimethylsilyloxy][(3aR,4aR,7aR,7bS)-3a,4a,7a,7b-tetrahydro-6,6-dimethyl[1,3]dioxolo[4,5]furo[2,3-d]isoxazol-3-yl]methyl}-6-endo-chloro-2-endo-(methoxymethoxy)-5-exo-(phenylseleno)-7-oxabicyclo[2.2.1]hep... 
• 263405-40-9 (+)-(1R,2R,3S,4R)-3-endo-{(S)-hydroxy[(3aR,4aR,7aR,7bS)-3a,4a,7a,7b-tetrahydro-6,6-dimethyl[1,3]dioxolo[4,5]furo[2,3-d]isoxazol-3-yl]methyl}-5-phenylseleno-7-oxabicyclo[2.2.1]hept-5-en-2-one 
• 263405-36-3 (1S,3R,4R,5R,6R)-6-endo-chloro-3-endo-{(S)-hydroxy[(3aR,4aR,7aR,7bS)-3a,4a,7a,7b-tetrahydro-6,6-dimethyl[1,3]dioxolo[4,5]furo[2,3-d]isoxazol-3-yl]methyl}-5-exo-(phenylseleno)-7-oxabicyclo[2.2.1]heptan-2-one 

Relevant academic research and scientific papers

THE ELECTRON-RELEASING HOMOCONJUGATED CARBONYL GROUP. APPLICATION TO THE TOTAL SYNTHESES OF 3-DEOXY-,4-DEOXY-HEXOSE,LIVIDOSAMINE AND DERIVATIVES

The regioselective electrophilic addition of benzeneselenyl bromide to (-)-(1S,4S)-7-oxabicyclo-hept-5-en-2-one were exploited to develop efficient syntheses of methyl 3-deoxy-α-D-arabino-hexofuranoside and 4-deoxy-D-lyxo-hexopyranose.Similarly, D-

Total asymmetric syntheses of d-lividosamine and 2-acetamido-2,3-dideoxy-d-arabino-hexose derivatives

The "naked sugar" (+)-(1R, 4R)-7-oxabicyclo[2.2.1]hept-5-en-one((+)-2) has been converted to D-lividosamine ((+)-1: 3-deoxy-D-glucosamine) and derivatives via (+)-2-chloro-2,3-dideoxy-5,6-O-isopropyridene-D-arabino-hexono-1,4-lactone ((+)-33) and (+)-2-az