128503-14-0

Upstream product

• 67-56-1 methanol 
• 128503-27-5 (-)-(1S,4S,5S,7S)-7-endo-chloro-3-oxo-2,8-dioxabicyclo<3.2.1>oct-4-exo-yl metachlorobenzoate 
• 88708-22-9 (+)-(1R,4R)-7-oxabicyclo<2.2.1>-hept-5-en-2-one 
• 128573-16-0 (-)-(1S,4R,5R,6R)-6-endo-chloro-5-exo-(phenylseleno)-7-oxabicyclo[2.2.1]heptan-2-one 
• 128503-25-3 (+)-(1S,2S,3R,4S)-5-chloro-3-exo-hydroxy-3-endo-<(tert-butyl)dimethylsilyloxy>-7-oxabicyclo<2.2.1>hept-5-en-2-exo-yl metachlorobenzoate 
• 128530-72-3 (-)-(1S,4R,5R,6R)-5-exo-benzeneselenyl-2-<(tert-butyl)dimethylsilyloxy>-6-endo-chloro-7-oxabicyclo<2.2.1>hept-2-ene 

Relevant academic research and scientific papers

THE ELECTRON-RELEASING HOMOCONJUGATED CARBONYL GROUP. APPLICATION TO THE TOTAL SYNTHESES OF 3-DEOXY-,4-DEOXY-HEXOSE,LIVIDOSAMINE AND DERIVATIVES

The regioselective electrophilic addition of benzeneselenyl bromide to (-)-(1S,4S)-7-oxabicyclo-hept-5-en-2-one were exploited to develop efficient syntheses of methyl 3-deoxy-α-D-arabino-hexofuranoside and 4-deoxy-D-lyxo-hexopyranose.Similarly, D-