128594-25-2

Basic information

• Product Name: bromo(tetracarbonyl)(propyldiphenylphosphane)manganese(I)
• CAS NO: 128594-25-2
• Molecular Weight: 475.157
• Mol File: 128594-25-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: bromo(tetracarbonyl)(propyldiphenylphosphane)manganese(I)(CAS DataBase Reference)
• NIST Chemistry Reference: bromo(tetracarbonyl)(propyldiphenylphosphane)manganese(I)(128594-25-2)
• EPA Substance Registry System: bromo(tetracarbonyl)(propyldiphenylphosphane)manganese(I)(128594-25-2)

Safety Data

• Hazardous Substances Data: 128594-25-2(Hazardous Substances Data)

Upstream product

• 14516-54-2 bromopentacarbonylmanganese(I) 
• 7650-84-2 diphenylphosphinopropane 

Relevant articles and documents

Darstellung und Eingenschaften von und Reaktionen mit metallhaltigen Heterocyclen LXX. Untersuchungen ueber den Zusammenhang zwischen Konformation und chemischer Verschiebung in Phosphametallacycloalkanen

To investigate the well known dependence of 31P NMR chemical shift values on the ring size of phosphametallacycloalkanes, we compared the series of cyclic and acyclic complexes, Br(OC)4MnPPh2(CH2)nH (1a-1d), (η5-C5H5)Cl(OC)2WPPh2(CH2)nH (2a-2c), (η5-C5H5)Me(OC)2WPPh2(CH2)nH (3a-3c), (4b-4d), (5b,5c) (n=2 (a), 3 (b), 4 (c), 5 (d)).Different conformations have an obvious influence on the 31P and 13C chemical shift of metal adjacent ring atoms.The structure of phosphawolframacyclopentane (5b) in solution differs from the crystaline state.