128625-99-0

Basic information

• Product Name: Benzyl 2,3-O-Isopropyliden-α-D-lyxo-hexodialdofuranosid(1,4)
• Synonyms: Benzyl 2,3-O-Isopropyliden-α-D-lyxo-hexodialdofuranosid(1,4)
• CAS NO: 128625-99-0
• Molecular Weight: 292.332
• Mol File: 128625-99-0.mol

Chemical Properties

• CAS DataBase Reference: Benzyl 2,3-O-Isopropyliden-α-D-lyxo-hexodialdofuranosid(1,4)(CAS DataBase Reference)
• NIST Chemistry Reference: Benzyl 2,3-O-Isopropyliden-α-D-lyxo-hexodialdofuranosid(1,4)(128625-99-0)
• EPA Substance Registry System: Benzyl 2,3-O-Isopropyliden-α-D-lyxo-hexodialdofuranosid(1,4)(128625-99-0)

Safety Data

• Hazardous Substances Data: 128625-99-0(Hazardous Substances Data)

Upstream product

• 28978-37-2 1-O-benzyl-2,3-O-isopropylidene-5,6-di-O-mesyl-α-D-mannofuranose 
• 74911-90-3 phenylmethyl-2,3-O-(1-methylethylidene)-5,6-didehydro-5,6-dideoxy-α-D-mannofuranoside 
• 74911-93-6 phenylmethyl-2,3-O-(1-methylethylidene)-5-deoxy-α-D-mannofuranoside 

Relevant articles and documents

Pd(II)Cl2 mediated oxidative cyclisation of some 3-hydroxy 4-vinyl furanoside derivatives to synthetically valuable bis-furanosides

PdCl2 mediated oxidation of 3-hydroxy-4-vinylfuranosides (Ia-k) lead to the formation of aldehydes, some of them are 'in situ' trapped as their lactols (IIIa,c,e,f,h) and further converted to bis-furanoside lactones (IVa,c,e,f,h).

Synthese von (+)-Aspicilin mit Bausteinen aus nachwachsenden Rohstoffen

The 18-membered lichen macrolide (+)-aspicilin (1) is easily built up from compounds 14, 16, 3, and 24 following the C3 + C7 + C6 +C2 = C18 pattern (see Schemes).The synthesis requires 15 steps and gives 1 in 13percent overall yield from D-mannose (2).The