74911-90-3

Upstream product

• 74912-02-0 1-O-benzyl-2,3-O-isopropylidene-α-D-manno-furanose 
• 78039-06-2 phenylmethyl-2,3-O-(1-methylethylidene)-5,6-O-(N,N-dimethylaminomethylene)-α-D-mannofuranoside 
• 28978-37-2 1-O-benzyl-2,3-O-isopropylidene-5,6-di-O-mesyl-α-D-mannofuranose 

Downstream Products

• 74911-94-7 phenylmethyl-2,3-O-(1-methylethylidene)-5-deoxy-6-O-methoxymethyl-α-D-mannofuranoside 
• 77988-68-2 phenylmethyl-2,3-O-(1-methylethylidene)-5-deoxy-6-O--α-D-mannofuranoside 
• 128626-00-6 Benzyl 5-Deoxy-2,3-O-isopropyliden-6-O-(p-toluolsulfonyl)-α-D-mannofuranosid 
• 128625-99-0 Benzyl 2,3-O-Isopropyliden-α-D-lyxo-hexodialdofuranosid(1,4) 
• 74911-93-6 phenylmethyl-2,3-O-(1-methylethylidene)-5-deoxy-α-D-mannofuranoside 

Relevant academic research and scientific papers

Synthese von (+)-Aspicilin mit Bausteinen aus nachwachsenden Rohstoffen

The 18-membered lichen macrolide (+)-aspicilin (1) is easily built up from compounds 14, 16, 3, and 24 following the C3 + C7 + C6 +C2 = C18 pattern (see Schemes).The synthesis requires 15 steps and gives 1 in 13percent overall yield from D-mannose (2).The

Synthese totale des acides (+) et (-) nonactique a partir de carbohydrates

The synthesis of (-) and (+) nonactic acids (2a) and (2b) has been achieved starting from D-mannose (7) and D-gluono-γ-lactone (22) respectively.The key step in the synthesis is the -sigmatropic rearrangement of the silylated ketene-acetals IV leadin