1286280-47-4

Basic information

• Product Name: 4-(benzyloxy)-2-methoxy-1-vinylbenzene
• Synonyms: 4-(benzyloxy)-2-methoxy-1-vinylbenzene
• CAS NO: 1286280-47-4
• Molecular Weight: 240.302
• Mol File: 1286280-47-4.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 4-(benzyloxy)-2-methoxy-1-vinylbenzene(CAS DataBase Reference)
• NIST Chemistry Reference: 4-(benzyloxy)-2-methoxy-1-vinylbenzene(1286280-47-4)
• EPA Substance Registry System: 4-(benzyloxy)-2-methoxy-1-vinylbenzene(1286280-47-4)

Safety Data

• Hazardous Substances Data: 1286280-47-4(Hazardous Substances Data)

Upstream product

• 100-39-0 benzyl bromide 
• 18278-34-7 4-hydroxy-2-methoxybenzaldehyde 
• 58026-14-5 4-(benzyloxy)-2-methoxybenzaldehyde 
• 1779-49-3 Methyltriphenylphosphonium bromide 
• 2065-66-9 methyl-triphenylphosphonium iodide 

Downstream Products

• 1016984-83-0 C₁₆H₁₈O₄ 
• 1286280-66-7 [(R)-1-(4-benzyloxy-2-methoxy-phenyl)-2-hydroxy-ethyl]carbamic acid benzyl ester 
• 1372551-34-2 4-hydroxy-4-(3-(4-hydroxyphenyl)propyl)-3-methoxycyclohexa-2,5-dienone 
• 73731-86-9 4-(3-(4-hydroxyphenyl)propyl)-3-methoxyphenol 
• 1286280-29-2 (1S,2S)-2-phenyl-cyclopropanecarboxylic acid {(R)-1-[4-(2-ethyl-butoxy)-2-methoxy-phenyl]-2-hydroxy-ethyl}amide 
• 1286280-50-9 {(R)-1-[4-(2-ethyl-butoxy)-2-methoxy-phenyl]-2-hydroxy-ethyl}carbamic acid tert-butyl ester 
• 1286280-49-6 [(R)-2-hydroxy-1-(4-hydroxy-2-methoxy-phenyl)ethyl]carbamic acid tert-butyl ester 
• 1286280-48-5 [(R)-1-(4-benzyloxy-2-methoxy-phenyl)-2-hydroxy-ethyl]carbamic acid tert-butyl ester 

Relevant articles and documents

Concise synthesis of broussonone A

A concise and expeditious approach to the total synthesis of broussonone A, a p-quinol natural compound, has been developed. The key features of the synthesis include the Grubbs II catalyst mediated cross metathesis of two aromatic subunits, and a chemoselective oxidative dearomatizationin the presence of two phenol moieties. Especially, optimization associated with the CM reaction of ortho-alkoxystyrenes was also studied, which are known to be ineffective for Ru-catalyzed metathesis reactions under conventional reaction conditions because ortho-alkoxy group could coordinate to the ruthenium center, resulting in the potential complication of catalyst inhibition.

Enantioselective total synthesis of hydramicromelin B

The first total synthesis of hydramicromelin B is described. An AuCl3/AgOTf-catalyzed intramolecular reaction was used as key step for the construction the coumarin ring.