128632-65-5

Upstream product

• 133604-43-0 (E)-(4S,5S)-5-Benzyloxy-5-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-4-methyl-pent-2-en-1-ol 
• 100572-69-8 (2R,3S,4S)-3-Bnzyloxy-1,2-O-isopropylidene-4-methyl-5-hexene-1,2-diol 
• 120040-77-9 (2R,3S)-3-Benzyloxy-3-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2-methyl-propionaldehyde 
• 133604-42-9 (E)-(4S,5S)-5-Benzyloxy-5-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-4-methyl-pent-2-enoic acid ethyl ester 

Downstream Products

• 133604-09-8 (3S,4S)-3-[(1R,2R)-2-Benzyloxy-2-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-1-methyl-ethyl]-heptadec-1-en-4-ol 
• 133695-39-3 (3R,4R)-3-[(1R,2R)-2-Benzyloxy-2-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-1-methyl-ethyl]-heptadec-1-en-4-ol 
• 133604-09-8 (2R,3S,4S,5S,6S)-3-O-benzyl-1,2-O-isopropylidene-4-methyl-5-vinylnonadecane-1,2,3,6-tetrol 
• 133695-26-8 (2R,3S,4S,5R,6R)-3-O-benzyl-1,2-O-isopropylidene-4-methyl-5-vinylnonadecane-1,2,3,6-tetrol 
• 133604-13-4 (2R,3S,4S,5S,6R,7S)-3-O-benzyl-7-O-((tert-butyldimethyl)silyl)-1,2-O-isopropylidene-4-methyl-5-vinyloctane-1,2,3,6,7-pentol 
• 128632-67-7 (3S,4R,5R)-3-[(1S,2S)-2-Benzyloxy-2-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-1-methyl-ethyl]-5-methoxymethoxy-non-1-en-4-ol 
• 133604-08-7 (2R,3S,4S,5S,6R)-3-O-benzyl-1,2-O-isopropylidene-4-methyl-6-phenyl-5-vinylhexane-1,2,3,6-tetrol 
• 133604-08-7 (2R,3S,4S,5R,6S)-3-O-benzyl-1,2-O-isopropylidene-4-methyl-6-phenyl-5-vinylhexane-1,2,3,6-tetrol 
• 133604-18-9 (2R,3S,4S,5R,6R,7S)-3-O-benzyl-1,2:6,7-di-O-isopropylidene-5-(hydroxymethyl)-4-methyloctane-1,2,3,6,7-pentol 
• 133604-17-8 (2'R,2S,3S,4S,5R)-4-(benzyloxy)-2-((2',2-isopropylidenedioxy)propyl)-3-methyl-5,6-(isopropylidenedioxy)hexanal 
• 133604-19-0 (2R,3S,4S,5R,6R,7S)-3-O-benzyl-1,2:6,7-di-O-isopropylidene-4-methyl-5-O-((methylsulfonyl)methyl)octane-1,2,3,6,7-pentol 
• 133604-14-5 (2R,3S,4S,5S,6R,7S)-3-O-benzyl-1,2-O-isopropylidene-4-methyl-5-vinyloctane-1,2,3,6,7-pentol 
• 133604-16-7 (2R,3S,4S,5S,6R,7S)-3-O-benzyl-1,2:6,7-di-O-isopropylidene-4-methyl-5-vinyloctane-1,2,3,6,7-pentol 
• 128632-69-9 (4R,5R)-4-{(S)-1-[(1S,2S)-2-Benzyloxy-2-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-1-methyl-ethyl]-allyl}-5-butyl-2,2-dimethyl-[1,3]dioxolane 

Relevant academic research and scientific papers

Highly Felkin-Anh Selective Hiyama Additions of Chiral Allylic Bromides to Aldehydes. Application to the First Synthesis of Nephromopsinic Acid and Its Enantiomer

The chromium(II)-mediated addition ("Hiyama reaction") of the chiral allylic bromides 13, 15, 19, 22, 24, and 27 to achiral and chiral aldehydes proceeds with high Felkin-Anh selectivity with respect to the stereocenter at Cγ in the bromide (Table II). By