128654-37-5Relevant academic research and scientific papers
Probing the role of an FeIV tetrazene in catalytic aziridination
Cramer, S. Alan,Snchez, Ral Hernndez,Brakhage, Desirae F.,Jenkins, David M.
, p. 13967 - 13970 (2014)
An iron(IV) tetrazene complex has been synthesized that is an important addition to a previously proposed catalytic aziridination cycle. It provides two key insights about the aziridination: an iron(IV) imide is formed and this imide can bind an additional ligand in the cis position.
Catalytic aziridination with alcoholic substrates: via a chromium tetracarbene catalyst
Keller, C. Luke,Kern, Jesse L.,Terry, Bradley D.,Roy, Sharani,Jenkins, David M.
supporting information, p. 1429 - 1432 (2018/02/19)
The first examples of aziridination catalysis with a chromium complex are communicated. This tetracarbene chromium complex provides novel catalytic aziridination reactions with protic substrates such as alcohols or amines on the alkene or organic azide an
Reactions of Aryl Azides with Alkenes in the Presence of Aluminium Trichloride. Formation of Novel Aziridines fused to Seven- and Eight-membered Rings
Takeuchi, Hiroshi,Shiobara, Yukihiko,Kawamoto, Hideyuki,Koyama, Kikuhiko
, p. 321 - 327 (2007/10/02)
Reactions of aryl azides (1) with cyclohexene gave 3-(arylamino)cyclohexenes (2) and trans-1-chloro-2-(arylamino)cyclohexanes (3), whereas that of (1) with cycloheptene or cis-cyclo-octene afforded novel aziridines, 8-aryl-8-azabicyclooctanes (4), or 9-aryl-9-azabicyclononanes (5), respectively.The reaction of phenyl azide (1a) with cis-4-methylpent-2-ene yielded 3-anilino-2-chloro-4-methylpentane (10), but that with the trans-alkene gave 4-anilino-2-methylpent-2-ene (7) and 3-anilino-4-methylpent-1-ene (8).The similar reaction of (1) with 3-trimethylsilylcyclohexene or 3-trimethylsilyl-cis-cyclo-octene produced only (2) or 3-(arylamino)-cis-cyclo-octenes (2').The formation of the aziridines or the ring-opened products was explained by a mechanism via an aziridinium-AlCl3 complex formed from an azide-AlCl3 complex.
