128702-25-0

Basic information

• Product Name: Methyl 2,2'-dihydroxy-7'-methoxy-1,1'-binaphthalene-3-carboxylate
• CAS NO: 128702-25-0
• Molecular Weight: 374.393
• Mol File: 128702-25-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Methyl 2,2'-dihydroxy-7'-methoxy-1,1'-binaphthalene-3-carboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: Methyl 2,2'-dihydroxy-7'-methoxy-1,1'-binaphthalene-3-carboxylate(128702-25-0)
• EPA Substance Registry System: Methyl 2,2'-dihydroxy-7'-methoxy-1,1'-binaphthalene-3-carboxylate(128702-25-0)

Safety Data

• Hazardous Substances Data: 128702-25-0(Hazardous Substances Data)

Upstream product

• 883-99-8 3-hydroxy-2-naphthoic acid methyl ester 
• 5060-82-2 7-methoxy-2-naphthol 

Relevant articles and documents

The oxidative cross-coupling of substituted 2-naphthols. Part I: The scope and limitations

Highly selective oxidative cross-coupling of differently substituted 2-naphthols mediated by Cu(II)-tert-butyl amine complexes is described. The 'cross'-products are obtained in good to excellent yields and the selectivity up to >90% is observed depending on the substitution of naphthol nuclei. The alternative procedures - the cross-coupling of free naphthols with CuCl(OMe) as well as the coupling of sodium naphtholates with anhydrous copper(II) chloride - were also studied. All these methods enable a simple and high-yield access to the unsymmetrically substituted binaphthols. A successful optical resolution of methyl 2,2'-dihydroxy-1,1'-binaphthalene-3-carboxylate by means of liquid chromatography on triacetylcellulose and the subsequent configurational correlation with a binaphthol derivative of known absolute configuration is reported.