128707-15-3

Upstream product

• 4613-62-1 3-deoxy-1,2;5,6-di-O-isopropylidene-α-D-glucofuranoside 
• 4005-46-3 3-deoxy-1,2-O-isopropylidene-D-glucose 
• 128651-43-4 Toluene-4-sulfonic acid (R)-1-((3aR,5S,6aR)-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-hexyl ester 
• 128651-42-3 (R)-1-((3aR,5S,6aR)-2,2-Dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-hexan-1-ol 
• 128651-44-5 (2S,3S,5R)-5-[1,3]Dioxolan-2-yl-2-pentyl-tetrahydro-furan-3-ol 
• 2457-93-4 (3aR,5S,6aR)-2,2-dimethyl-5-[(2R)-oxiran-2-yl]-3a,5,6,6a-tetrahydrofuro[2,3-d] [1,3]dioxole 
• 221187-63-9 (2S,3R,5R)-5-Benzyloxymethyl-2-pentyl-tetrahydro-furan-3-ol 
• 221187-58-2 (2S,5R)-5-Benzyloxymethyl-2-pentyl-dihydro-furan-3-one 
• 1035797-60-4 2-pentyl-3-(toluene-4-sulfonyl)-oxirane 
• 177213-31-9 1-[((Z)-Hept-1-ene)-1-sulfonyl]-4-methyl-benzene 
• 82721-81-1 1-(p-toluenesulfonyl)-1-heptyne 
• 65-85-0 benzoic acid 
• 628-71-7 1-Heptyne 
• 66-25-1 hexanal 

Relevant academic research and scientific papers

Highly diastereoselective Katsuki-Jacobsen oxidation-epoxidation of α-silyloxy sulfinyl dienes: Synthetic applications

(Chemical Equation Presented) Katsuki-Jacobsen oxidation-epoxidation of acyclic α-silyloxy sulfinyl dienes, followed by acid-promoted cyclization, leads to 2,5-trans-sulfonyl dihydrofurans with good selectivities. As an application, the formal syntheses of (6S,7S,9R,10R)- and (6S,7S,9S,10S)-6,9- epoxynonadec-18-ene-7,10-diols is reported.

Katsuki-Jacobsen oxidation-epoxidation of α-silyloxy sulfinyl dienes: application to the formal synthesis of (6S,7S,9R,10R)-6,9-epoxynonadec-18-ene-7,10-diol

The Katsuki-Jacobsen oxidation-epoxidation of acyclic α-silyloxy sulfinyl dienes, followed by acid-promoted cyclization, leads to 2,5-trans sulfonyl dihydrofurans with good selectivities. As an application, the formal synthesis of (6S,7S,9R,10R)-6,9-epoxy

Synthesis of (6S,7S,9R,10R)-6,9-epoxynonadec-18-ene-7,10-diol, a marine epoxy lipid isolated from the brown alga, Notheia anomala, by an oxiranyl anion strategy

The stereocontrolled synthesis of (6S,7S,9R,10R)-6,9-epoxynonadec-18- ene-7,10-diol, isolated from the brown alga, Notheia anomala, has been achieved. The key 2,3,5-trisubstituted tetrahydrofuran ring was constructed by alkylation of the sulfonyl-stabilized oxiranly anion followed by 5-endo cyclization.

A FORMAL TOTAL SYNTHESIS OF (6S,7S,9R,10R)-6,9-EPOXYNONADEC-18-ENE-7,10-DIOL FROM D-GLUCOSE

An enantiospecyfic synthesis of (2R,4S,5S)-tetrahydro-4-hydroxy-5-pentyl-2-furfuraldehyde (benzoate) (2) and (benzylate) (3), key intermediates in the synthesis of the title marine natural product (1) from D-glucose is described.