128756-55-8Relevant academic research and scientific papers
FURTHER STUDIES ON CARBON-CARBON BOND FORMATION BASED ON THE RADICAL REACTIONS OF ACYL DERIVATIVES OF N-HYDROXY-2-THIOPYRIDONE
Barton, Derek H. R.,Sarma, Jadab C.
, p. 1965 - 1968 (2007/10/02)
By careful exclusion of oxygen, carbon radicals, generated from the W lamp photolysis of O-acyl derivatives of N-hydroxy-2-thiopyridone, can be added efficiently to methylvinyl ketone.Extension to the radical from pent-4-enoic acid provides another synthesis of cyclopentane derivatives.Analogous additions with other electrophilic olefins are also reported.
