1287718-15-3Relevant articles and documents
Asymmetric synthesis of 1,3-diamines. II: Diastereoselective reduction of atropisomeric N-tert -butanesulfinylketimines
Martjuga, Marina,Belyakov, Sergey,Liepinsh, Edvards,Suna, Edgars
, p. 2635 - 2647 (2011/06/20)
Chiral, nonracemic o-aminobenzylamines were prepared in a highly diastereoselective reduction of atropisomeric N-tert-butanesulfinylketimines. The ortho-substituent ensures the distinct reactivity of atropisomers 4d-f. The free energy of activation for at