128800-00-0

Basic information

• Product Name: S-Benzyl S-(2-methylallyl) dithiocarbonate
• CAS NO: 128800-00-0
• Molecular Weight: 238.375
• Mol File: 128800-00-0.mol

Chemical Properties

• CAS DataBase Reference: S-Benzyl S-(2-methylallyl) dithiocarbonate(CAS DataBase Reference)
• NIST Chemistry Reference: S-Benzyl S-(2-methylallyl) dithiocarbonate(128800-00-0)
• EPA Substance Registry System: S-Benzyl S-(2-methylallyl) dithiocarbonate(128800-00-0)

Safety Data

• Hazardous Substances Data: 128800-00-0(Hazardous Substances Data)

Downstream Products

• 101561-50-6 benzyl 2-methylprop-2-en-1-yl sulfide 

Relevant articles and documents

Stereoselective formation of allylic sulfides via two sequential [3,3]-sigmatropic rearrangements of allylic xanthates and its mechanistic aspects

O-(2-Alkenyl) S-alkyl dithiocarbonates (allylic xanthates) were pyrolyzed to give 2-alkenyl alkyl sulfides (allylic sulfides) via the corresponding allylically isomeric S-(2-alkenyl) S-alkyl dithiocarbonates. The reaction follows the first-order rate law

A CONVENIENT AND STEREOSELECTIVE SYNTHESIS OF ALLYLIC SULFIDES

The fractional distillation of O-(2-alkenyl or 2-cycloalkenyl) S-alkyl dithiocarbonates (xanthates) affords 2-alkenyl or 2-cycloalkenyl alkyl sulfides.The reaction involves the -sigmatropic rearrangement of the xanthates to produce S-(2-alkenyl or 2-cycloalkenyl) S-alkyl dithiocarbonates followed by extrusion of carbon oxysulfide to give 2-alkenyl or 2-cycloalkenyl alkyl sulfides.