128930-50-7Relevant academic research and scientific papers
The Chemistry of Niobium and Tantalum Dithiocarbamato-complexes. Part 3. Protonation of (R=Me or Ph)
Henderson, Richard A.,Oglieve, Kay E.
, p. 1093 - 1096 (1990)
The reactions of (R=Me or Ph) with an excess of anhydrous HBr have been studied in MeCN.The reactions, which yield and the corresponding substituted hydrazine, occur in two stages: the first is the initial rapid for
The Chemistry of Niobium and Tantalum Dithiocarbamato-complexes. Part 5. The Kinetics and Mechanism of the Hydrazine-forming Reactions between 2(μ-N2)> (M=Nb or Ta) and Acid: Rate-limiting Protonation
Henderson, Richard A.,Morgan, Susan H.,Stephens, Alan N.
, p. 1101 - 1106 (2007/10/02)
The kinetics of the reaction between 3>2(μ-N2)> and HX (M=Nb, X=Cl or Br; M=Ta, X=Cl) to yield and hydrazine have been studied in MeCN at 25.0 deg C.In all cases the multistep mechanism involves rate-limiting protonation of the
