1289401-33-7Relevant academic research and scientific papers
cis-2,5-diaminobicyclo[2.2.2]octane, a new scaffold for asymmetric catalysis via salen-metal complexes
White, James D.,Shaw, Subrata
, p. 2488 - 2491 (2011)
Chemical equations presented. A new C2 symmetric salen scaffold based on cis-2,5-diaminobicyclo[2.2.2]octane has been synthesized that forms complexes with a wide range of metals. The chromium(III) complex is shown to catalyze the hetero-Diels-
Synthesis of axially chiral C10-BridgePHOS oxides and their use as organocatalysts in enantioselective allylations of aldehydes
Chen, Jianzhong,Liu, Delong,Fan, Dongyang,Liu, Yangang,Zhang, Wanbin
, p. 8161 - 8168 (2013/09/02)
A series of C10-BridgePHOS oxides possessing different substituted groups on the diphenyl phosphine system were synthesized and tested as organocatalysts in the allylation of aldehydes with allyltrichlorosilane, providing chiral homoallylic alc
