83-38-5

Basic information

• Product Name: 2,6-Dichlorobenzaldehyde
• Synonyms: LABOTEST-BB LT01460902;AURORA 14017;2,6-DICHLOROBENZALDEHYDE;AKOS BBS-00003170;2,6-dichloro-benzaldehyd;o,o'-dichlorobenzaldehyde;2,6-Dichlor-Benzaldehyd;2,6-Dichloobenzaldehyde
• CAS NO: 83-38-5
• Molecular Formula: C₇H₄Cl₂O
• Molecular Weight: 175.01
• EINECS: 201-472-2
• Product Categories: Benzaldehyde;Dicloxacillin;Aldehydes;C7;Carbonyl Compounds;Aromatics;Intermediates;Building Blocks;Carbonyl Compounds;Chemical Synthesis;Organic Building Blocks
• Mol File: 83-38-5.mol
• Article Data: 98

Chemical Properties

• Melting Point: 69-71 °C(lit.)
• Boiling Point: 165°C
• Flash Point: 135°C
• Appearance: White to light beige/Crystalline Powder
• Density: 1.3456 (rough estimate)
• Vapor Pressure: 0.0406mmHg at 25°C
• Refractive Index: 1.5756 (estimate)
• Storage Temp.: Store below +30°C.
• Solubility: <1g/l insoluble
• Water Solubility: <0.1 g/100 mL at 23℃
• Sensitive: Air Sensitive
• Stability: Stable. Incompatible with strong oxidizing agents, strong bases. Air, light and moisture sensitive.
• BRN: 386477
• CAS DataBase Reference: 2,6-Dichlorobenzaldehyde(CAS DataBase Reference)
• NIST Chemistry Reference: 2,6-Dichlorobenzaldehyde(83-38-5)
• EPA Substance Registry System: 2,6-Dichlorobenzaldehyde(83-38-5)

Safety Data

• Hazard Codes: C,Xi
• Statements: 34-36/37/38
• Safety Statements: 26-27-28-36/37/39-45-37/39
• RIDADR: UN 3261 8/PG 2
• WGK Germany: 2
• TSCA: Yes
• HazardClass: 8
• PackingGroup: III
• Hazardous Substances Data: 83-38-5(Hazardous Substances Data)

Usage

Chemical Properties

white to light yellow powder

Uses

Different sources of media describe the Uses of 83-38-5 differently. You can refer to the following data:
1. An intermediate in the synthesis of substituted (2,6-dichlorobenzylideneamino)guanidines and some hydrazone derivatives of C-cyanoformamidrazone. It
2. An intermediate in the synthesis of substituted (2,6-dichlorobenzylideneamino)guanidines and some hydrazone derivatives of C-cyanoformamidrazone. It showed antihypertensive activity.

Synthesis Reference(s)

Journal of the American Chemical Society, 78, p. 4609, 1956 DOI: 10.1021/ja01599a025Tetrahedron Letters, 29, p. 707, 1988 DOI: 10.1016/S0040-4039(00)80190-2

General Description

Yellowish flakes or fine off-white powder. Pungent odor.

Air & Water Reactions

Sensitive to air, moisture and light. Insoluble in water.

Reactivity Profile

2,6-Dichlorobenzaldehyde is incompatible with strong oxidizers and strong bases. 2,6-Dichlorobenzaldehyde may also be incompatible with iron.

Fire Hazard

2,6-Dichlorobenzaldehyde is combustible.

Purification Methods

Crystallise the aldehyde from EtOH/H2O or pet ether (b 30-60o). [Beilstein 7 IV 576.]

InChI:InChI=1/C7H4Cl2O/c8-6-2-1-3-7(9)5(6)4-10/h1-4H

Synthetic route

2,6-dichlorobenzyl alcohol (15258-73-8) → 2,6-dichlorobenzaldehyde (83-38-5)

Conditions	Yield
With dmap; tetrakis(actonitrile)copper(I) hexafluorophosphate; N,N'-di-tert-butylethylenediamine; oxygen In dichloromethane at 20℃; under 760.051 Torr; for 3h; Schlenk technique; Molecular sieve; Sealed tube;	99%
With tert.-butylnitrite; oxygen; acetic acid In toluene at 50℃; for 8.5h;	99%
With 2,2'-azobis(isobutyronitrile); oxygen; sodium bromide In 1,4-dioxane at 70℃;	94%

2,6-Dichlorobenzaldehyde N,N-dimethylhydrazone (2828-47-9) → 2,6-dichlorobenzaldehyde (83-38-5)

Conditions	Yield
With 3-benzyl-5-(2-hydroxyethyl)-4-methyl-1,3-thiazol-3-ium chloride In chloroform at 20℃; for 1h; oxidative cleavage;	98%
With chloro-trimethyl-silane; sodium iodide In water; acetonitrile for 0.0333333h; deprotection;	94%
With triethylene diamine nickel thiosulfate; water In chloroform at 20℃; for 0.166667h; Hydrolysis;	94%
With iron(II) sulfate In chloroform at 20℃; for 0.75h; Hydrolysis;	88%

2,6-dichlorobenzaldoxime (25185-95-9) → 2,6-dichlorobenzaldehyde (83-38-5)

Conditions	Yield
With Cr-MCM-41 zeolite on silica gel for 0.1h; microwave irradiation;	98%
With 2,6-dicarboxypyridinium fluorochromate for 0.5h;	96%
With potassium permanganate; 1-n-butyl-3-methylimidazolim bromide at 20℃; for 0.383333h; Ionic liquid; chemoselective reaction;	91%

2-chloro-benzaldehyde (89-98-5) → 2,6-dichlorobenzaldehyde (83-38-5)

Conditions	Yield
With N-chloro-succinimide; palladium diacetate; silver trifluoroacetate; anthranilic acid; trifluoroacetic acid In 1,2-dichloro-ethane at 60℃; for 24h; Sealed tube;	95%
With N-chloro-succinimide; 2-hydroxyl-5-nitro-3-(trifluoromethyl)pyridine; 4-trifluoromethylphenylamine; palladium diacetate; trifluoroacetic acid In 1,2-dichloro-ethane at 80℃; for 24h; Sealed tube;	92%

1,3-Dichloro-2-chloromethyl-benzene (2014-83-7) → 2,6-dichlorobenzaldehyde (83-38-5)

Conditions	Yield
With dihydrogen peroxide; trimethylamine In water for 2h; Reflux;	94%

2-(2,6-dichlorophenyl)-1,3-dithiane → 2,6-dichlorobenzaldehyde (83-38-5)

Conditions	Yield
With 1,3,5-trichloro-2,4,6-triazine; dimethyl sulfoxide In dichloromethane at 20℃; for 2.15h;	91%

2,6-Dichlorbenzaldehyd-2,4-dinitrophenylhydrazon (51379-82-9) → 2,6-dichlorobenzaldehyde (83-38-5)

Conditions	Yield
With potassium permanganate at 40℃; for 2.8h; Ionic liquid; chemoselective reaction;	81%

2,6-dichlorobenzaldehyde dimethyl acetal → 2,6-dichlorobenzaldehyde (83-38-5)

Conditions	Yield
With β‐cyclodextrin In methanol; water at 50℃; for 10h;	80%

1,3-dichloro-2-methoxymethylbenzene (33486-90-7) → 2,6-dichlorobenzaldehyde (83-38-5)

Conditions	Yield
With N-Bromosuccinimide In tetrachloromethane for 1h; Irradiation; Reflux;	77%

2-(2,6-dichlorophenyl)-1,3-dioxolane (82073-58-3) + triphenylphosphine hydrobromide (6399-81-1) → 2,6-dichlorobenzaldehyde (83-38-5) + 2-(hydroxyethyl)triphenylphosphonium bromide (7237-34-5)

Conditions	Yield
In dichloromethane at 50℃; for 0.0833333h; Microwave irradiation; Sealed tube;	A 76% B n/a

2,6-dichlorobenzaldehyde (2,6-dichlorobenzylidene)hydrazone (32188-71-9) → 2,6-dichlorobenzaldehyde (83-38-5)

Conditions	Yield
With ammonium cerium(IV) nitrate In water; acetonitrile at 50℃; for 15h; Oxidation;	57%

d,l-1,2-Bis(2,6-dichlorphenyl)-N,N'-diethylethylendiamin (74105-85-4) → 2,6-dichlorobenzaldehyde (83-38-5) + 4-Chlor-2-(2,6-dichlorphenyl)-1-ethylindol (74105-78-5) + 4,9-Dichlor-5,10-diethyl-4b,5,9b,10-tetrahydroindolo<3,2-b>indol (74105-79-6)

Conditions	Yield
at 215℃; for 0.25h;	A 4% B 53% C 22%

(2,6-dichlorobenzylidene)aniline (104669-26-3, 33629-92-4) → 2,6-dichlorobenzaldehyde (83-38-5)

Conditions	Yield
With hydrogenchloride; water In diethyl ether; toluene at 20℃; for 2h; Inert atmosphere;	32%

2,6-dichloro-N,N-diethylbenzamide (10345-78-5) → 2,6-dichlorobenzaldehyde (83-38-5)

Conditions	Yield
With Schwartz's reagent In tetrahydrofuran at 20℃; for 18h;	17%

2,6-dichlorobenzyl azide → 2,6-dichlorobenzaldehyde (83-38-5)

Conditions	Yield
With sodium dithionite; spermwhale myoglobin (H64V,V68A) In methanol; aq. phosphate buffer at 20℃; for 24h; pH=7; Catalytic behavior;	1%
With sodium dithionite In methanol; aq. phosphate buffer at 20℃; for 24h; pH=7; Catalytic behavior; Enzymatic reaction;

2,6-dichloro-benzaldehyde-[N-(4-dimethylamino-phenyl)-oxime ] (115231-29-3) → 2,6-dichlorobenzaldehyde (83-38-5)

Conditions	Yield
With sulfuric acid

2,6-dichlorobenzalchloride (81-19-6) → 2,6-dichlorobenzaldehyde (83-38-5)

Conditions	Yield
With sulfuric acid anschliessenden Behandeln mit Eis;
With ethanol; silver nitrate

guanabenz (60329-03-5) → 2,6-dichlorobenzaldehyde (83-38-5) + aminoguanidine (79-17-4)

Conditions	Yield
With hydrogenchloride In water at 37℃; for 10h; effect of pH on the reversibility;

C16H10Cl4O3 → 2,6-dichlorobenzaldehyde (83-38-5)

Conditions	Yield
Yield given. Multistep reaction;

N,N-dimethyl-formamide (68-12-2, 33513-42-7) + 1,3-Dichlorobenzene (541-73-1) → 2,6-dichlorobenzaldehyde (83-38-5)

Conditions	Yield
With n-butyllithium 1.) hexane,THF, -65 to -70 deg C, 45 min, 2.) THF, -70 deg C, 45 min; Yield given. Multistep reaction;
Stage #1: 1,3-Dichlorobenzene With n-butyllithium; N,N,N,N,-tetramethylethylenediamine; diisopropylamine In tetrahydrofuran at -78℃; for 1h; Inert atmosphere; Stage #2: N,N-dimethyl-formamide at -78℃; for 0.5h; Inert atmosphere; regioselective reaction;
Stage #1: 1,3-Dichlorobenzene With lithium diisopropyl amide In 1,2-dimethoxyethane; n-heptane; ethylbenzene at -60℃; for 1h; Stage #2: N,N-dimethyl-formamide In 1,2-dimethoxyethane; n-heptane; ethylbenzene at -60℃; for 0.5h; Cooling with ice;

1,2-di-(2,6-dichlorophenyl)-1,2-ethanediol (112792-78-6) → 2,6-dichlorobenzaldehyde (83-38-5)

Conditions	Yield
With 1-Benzyl-1,4-dihydronicotinamide; oxygen; meso-tetraphenylporphyrin iron(III) chloride In dichloromethane for 12h; Ambient temperature; Irradiation;	20 % Chromat.

2,6-dichlorobenzaldehyde (83-38-5) → 2,6-dichlorobenzaldoxime (25185-95-9)

Conditions	Yield
With hydroxylamine hydrochloride	100%
With pyridine; hydroxylamine hydrochloride at 20℃; for 0.166667h;	100%
With pyridine; hydroxylamine hydrochloride at 20℃; for 0.166667h;	100%

2,6-dichlorobenzaldehyde (83-38-5) → (1E)-2,6-dichlorobenzaldehyde oxime (6575-28-6)

Conditions	Yield
With pyridine; hydroxylamine hydrochloride In ethanol	100%
With hydroxylamine hydrochloride; sodium hydroxide In ethanol; water at 80 - 90℃; for 18 - 24h;	96%
With hydroxylamine hydrochloride; sodium hydroxide In ethanol; water at 90℃; for 24h;	96%

cyclohexanone (108-94-1) + 2,6-dichlorobenzaldehyde (83-38-5) → (2S,1'R)-2-[(2,6-dichlorophenyl)hydroxymethyl]cyclohexan-1-one

Conditions	Yield
With C18H17F6N5; 2,4-dinitrobenzoic acid In neat (no solvent) at 0℃; for 48h; Aldol Addition;	100%
With C35H55N3O5; water at -20℃; for 24h; Aldol Condensation; enantioselective reaction;	99%
trans-4-hydroxy-L-prolinamide derivative In water at 25℃; for 5h;	95%

ethyl acetoacetate (141-97-9) + 2,6-dichlorobenzaldehyde (83-38-5) → 2-(2,6-dichlorophenyl)-4-hydroxy-4-methyl-6-oxo-cyclohexane-1,3-dicarboxylic acid diethyl ester (371981-20-3)

Conditions	Yield
With piperidine In ethanol at 20℃;	100%
With piperidine In ethanol Inert atmosphere;	68%

cis, trans-1,3-dimethylaminocyclohexane (2579-20-6) + 2,6-dichlorobenzaldehyde (83-38-5) → C22H22Cl4N2 (1217526-98-1)

Conditions	Yield
In methanol at 20℃; Molecular sieve;	100%
In methanol at 20℃; Molecular sieve;

1,3-dimethylbarbituric acid (769-42-6) + 2,6-dichlorobenzaldehyde (83-38-5) + dimedone (126-81-8) + diethylamine (109-89-7) → C21H22Cl2N2O5*C4H11N

Conditions	Yield
In water at 20℃; Inert atmosphere;	100%

2,6-dichlorobenzaldehyde (83-38-5) + dimedone (126-81-8) + diethylamine (109-89-7) → Diethylammonium 2-((2,6-dichlorophenyl)(2-hydroxy-4,4-dimethyl-6-oxocyclohex-1-en-1-yl)methyl)-5,5-dimethyl-3-oxocyclohex-1-enolate

Conditions	Yield
In water at 20℃; Inert atmosphere;	100%

2,6-dichlorobenzaldehyde (83-38-5) + ethanethiol (75-08-1) → C9H9ClOS (1186033-44-2)

Conditions	Yield
Stage #1: ethanethiol With sodium hydroxide In water at 20℃; for 0.5h; Stage #2: 2,6-dichlorobenzaldehyde With tetrabutylammomium bromide In water at 82℃;	99.4%
Stage #1: ethanethiol With sodium hydroxide In water for 1h; Stage #2: 2,6-dichlorobenzaldehyde With tetrabutylammomium bromide In water for 4h; Reflux;

2,6-dichlorobenzaldehyde (83-38-5) + malononitrile (109-77-3) → 2-(2,6-dichlorobenzylidene)malononitrile (2972-79-4)

Conditions	Yield
In water at 20℃; for 0.166667h; Knoevenagel Condensation; Green chemistry;	99%
With ZnO/Al-SBA-15 (40) In ethanol at 20℃; for 2h; Knoevenagel Condensation; Green chemistry;	97%
With zirconium(IV) oxide In ethanol for 2h; Knoevenagel Condensation; Reflux;	95%

2,6-dichlorobenzaldehyde (83-38-5) → 2,6-dichlorobenzyl alcohol (15258-73-8)

Conditions	Yield
With sodium tetrahydroborate In methanol at 0℃;	99%
With sodium tetrahydroborate In ethanol at 20℃; for 2h;	94%
With Triethoxysilane; C27H42FeP4S In tetrahydrofuran at 50℃; for 2h; Catalytic behavior; Schlenk technique; Green chemistry;	93%

2,6-dichlorobenzaldehyde (83-38-5) + 4-acetylbenzenesulfonyl-Rink resin → 4-[(2E)-3-(2,6-dichlorophenyl)prop-2-enoyl]benzenesulfonamide

Conditions	Yield
Stage #1: 2,6-dichlorobenzaldehyde; 4-acetylbenzenesulfonyl-Rink resin With sodium ethanolate In tetrahydrofuran; ethanol at 20℃; for 0.5h; Stage #2: With trifluoroacetic acid In dichloromethane Further stages.;	99%

2,6-dichlorobenzaldehyde (83-38-5) + Trimethylenediamine (109-76-2) → N,N'-bis(2,6-dichlorobenzylidene)propane-1,3-diamine (348630-62-6)

Conditions	Yield
In ethanol for 0.5h; Heating;	99%
In benzene for 24h; Heating;	72.07%

2,6-dichlorobenzaldehyde (83-38-5) → 2,4,5-tris(2,6-dichlorophenyl)-4,5-dihydro-1H-imidazole

Conditions	Yield
With ammonium chloride In ethanol at 20℃; for 192h;	99%

3-chloro-1,1-dimethylpropylamine hydrochloride (686746-12-3) + 2,6-dichlorobenzaldehyde (83-38-5) → (3-chloro-1,1-dimethylpropyl)-(2,6-dichlorobenzylidene)-amine (686746-13-4)

Conditions	Yield
Stage #1: 3-chloro-1,1-dimethylpropylamine-hydrochloride With sodium hydroxide In water at 0℃; for 0.5h; Stage #2: 2,6-dichlorobenzaldehyde In dichloromethane at 20℃; for 18h;	99%

2,6-dichlorobenzaldehyde (83-38-5) + allyl-trimethyl-silane (762-72-1) → 1,3-dichloro-2-[1-[(trimethylsilyl)oxy]-3-buten-1-yl]benzene (1200328-43-3)

Conditions	Yield
With Montmorillonite K10 clay In dichloromethane at 0 - 20℃; for 1.08333h; Hosomi-Sakurai reaction;	99%
With C76H92CoN4(1+)*F6Sb(1-) In 1,2-dichloro-ethane at 100℃; for 4h; Sealed tube;

cyclohexanone (108-94-1) + 2,6-dichlorobenzaldehyde (83-38-5) → 2-[hydroxy-(2,6-dichlorophenyl)-methyl]-cyclohexan-1-one

Conditions	Yield
With (S)-N-( p-dodecylphenylsulfonyl)-2-pyrrolidinecarboxamide; water In 1,2-dichloro-ethane at 20℃; for 48h; Aldol condensation; optical yield given as %ee; enantioselective reaction;	99%

3-(dimethylcarbamothioyl)-1-methyl-1H-imidazol-3-ium chloride (161149-23-1) + 2,6-dichlorobenzaldehyde (83-38-5) → O-(2,6-dichlorophenyl)(1-methyl-1H-imidazol-2-yl)methyl dimethylcarbamothioate (1413413-86-1)

Conditions	Yield
With triethylamine In N,N-dimethyl-formamide at 30℃; for 12h; Temperature; Inert atmosphere;	99%

(4R,5R)-4-benzyloxycarbonylamino-5-isopropylpyrazolidin-3-one + 2,6-dichlorobenzaldehyde (83-38-5) → (3R,4R,Z)-4-(benzyloxycarbonylamino)-2-(2,6-dichlorobenzylidene)-3-isopropyl-5-oxopyrazolidin-2-ium-1-ide

Conditions	Yield
Stage #1: (4R,5R)-4-benzyloxycarbonylamino-5-isopropylpyrazolidin-3-one; 2,6-dichlorobenzaldehyde In methanol at 20℃; for 0.0833333h; Stage #2: With trifluoroacetic acid In methanol at 20℃; for 7h;	99%

1-ethynyl-3-methyl-benzene (766-82-5) + 2,6-dichlorobenzaldehyde (83-38-5) → C16H12Cl2O (1590443-25-6)

Conditions	Yield
With 2,2,2-Trifluoroacetophenone; triphenylphosphine In water at 60℃; for 2h; Schlenk technique; Inert atmosphere; Green chemistry;	99%

4-benzyloxycarbonylamino-5-isopropyl-3-pyrazolidinone + 2,6-dichlorobenzaldehyde (83-38-5) → (3R,4R,Z)-4-(benzyloxycarbonylamino)-2-(2,6-dichlorobenzylidene)-3-isopropyl-5-oxopyrazolidin-2-ium-1-ide

Conditions	Yield
With trifluoroacetic acid In methanol	99%

methanol (67-56-1) + 2,6-dichlorobenzaldehyde (83-38-5) → 2,6-dichlorobenzaldehyde dimethyl acetal

Conditions	Yield
With Eosin Y In acetonitrile at 20℃; for 12h; Schlenk technique; Inert atmosphere; Irradiation; chemoselective reaction;	99%
With titanium tetrachloride; triethylamine In dichloromethane at 0 - 20℃; for 0.5h; Inert atmosphere;	93%

2,6-dichlorobenzaldehyde (83-38-5) + 4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane (25015-63-8) → 2-((2,6-dichlorobenzyl)oxy)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Conditions	Yield
With C34H28N6Zn In neat (no solvent) at 20℃; for 2h; Glovebox; Schlenk technique;	99%
With C24H34N5PSeTi In toluene at 30℃; for 3h; Glovebox; Schlenk technique; chemoselective reaction;	93%
With C45H69FeN8PSi2 In tetrahydrofuran at 20℃; for 6h; Inert atmosphere; Schlenk technique;

acetic anhydride (108-24-7) + 2,6-dichlorobenzaldehyde (83-38-5) → 1,1-diacetoxy-1-(2,6-dichlorophenyl)methane (24653-82-5)

Conditions	Yield
With p-toluenesulfonic acid-paraformaldehyde copolymer at 25℃; for 0.25h; Neat (no solvent);	98%
aluminium dodecatungsten phosphate at 20℃; for 0.25h;	95%
With lithium trifluoromethanesulfonate at 20℃; for 19h;	95%

2,6-dichlorobenzaldehyde (83-38-5) → 2,6-dichloro-benzonitrile (1194-65-6)

Conditions	Yield
With aluminum oxide; hydroxylamine hydrochloride; methanesulfonyl chloride at 100℃; for 0.333333h;	98%
With ammonia; oxygen In tert-Amyl alcohol at 40℃; under 750.075 Torr; for 24h; Green chemistry;	94%
With manganese(IV) oxide; ammonia; magnesium sulfate In tetrahydrofuran; isopropyl alcohol at 20℃; for 17h;	93%

2,6-dichlorobenzaldehyde (83-38-5) + tetraethyl (aminomethylene)bis(phosphonate) (80474-99-3) → [{[1-(2,6-Dichloro-phenyl)-meth-(E)-ylidene]-amino}-(diethoxy-phosphoryl)-methyl]-phosphonic acid diethyl ester

Conditions	Yield
In diethyl ether for 2h;	98%

2,6-dichlorobenzaldehyde (83-38-5) → 2,6-dichlorobenzaldoxime (3714-77-0)

Conditions	Yield
With hydroxylamine hydrochloride; titanium(IV) oxide at 80℃; for 0.166667h;	98%
With hydroxylamine hydrochloride; sodium hydroxide In ethanol; water at 0 - 20℃; for 2h;	96%
With cadmium sulfate; hydroxylamine hydrochloride for 0.0833333h; Microwave irradiation; stereoselective reaction;	85%
With hydroxylamine hydrochloride; potassium carbonate at 90℃; for 5h;	90 % Spectr.
With aluminum oxide; methanesulfonic acid at 80℃; for 0.0833333h;	95 % Spectr.

2,6-dichlorobenzaldehyde (83-38-5) + 2-amino-6-hydrazino-4-pyrrolidino-5-pyrimidinecarbonitrile (308356-30-1) → 2-Amino-4-{N'-[1-(2,6-dichloro-phenyl)-meth-(E)-ylidene]-hydrazino}-6-pyrrolidin-1-yl-pyrimidine-5-carbonitrile

Conditions	Yield
With acetic acid In ethanol for 1h; Heating;	98%

Upstream product

• 115231-29-3 2,6-dichloro-benzaldehyde-[N-(4-dimethylamino-phenyl)-oxime ] 
• 1194-65-6 2,6-dichloro-benzonitrile 
• 10345-78-5 N,N-diethyl-2,6-dichlorobenzamide 
• 6575-24-2 2-(2,6-dichlorophenyl)acetic acid 
• 37532-04-0 N'-(2,6-dichlorobenzylidene)-4-methylbenzene-1-sulfonohydrazide 
• 25185-95-9 2,6-dichlorobenzaldoxime 
• 24653-82-5 1,1-diacetoxy-1-(2,6-dichlorophenyl)methane 
• 859182-93-7 bis-(2,6,α-trichloro-benzyl)-ether 
• 6579-24-4 1-(2,6-dichlorobenzylidene)-2-phenylhydrazine 
• 32188-71-9 2,6-dichlorobenzaldehyde (2,6-dichlorobenzylidene)hydrazone 
• 2828-47-9 2,6-Dichlorobenzaldehyde N,N-dimethylhydrazone 
• 15258-73-8 2,6-dichlorobenzyl alcohol 
• 61875-53-4 2,6-dichlorophenylacetylchloride 
• 20443-98-5 2,6-Dichlorobenzyl bromide 

Downstream Products

• 138973-34-9 4-(2',6'-dichlorobenzylidene)-2-phenyl-4-oxazolone 
• 53066-19-6 1-(2',6'-dichlorophenyl)-ethanol 
• 52287-52-2 (E)-1,3-dichloro-2-(2-nitroethenyl)benzene 
• 20595-49-7 (2E)-3-(2,6-dichlorophenyl)prop-2-enoic acid 
• 15012-28-9 2'',6''-dichloro-3,3'-dimethyl-4-hydroxyfuchsone-5,5'-dicarboxylic acid 
• 54668-93-8 6,6'-dihydroxy-5,5'-dimethyl-3,3'-(2,6-dichloro-benzylidene)-di-benzoic acid 
• 55327-52-1 4-chloro-N-(2,6-dichloro-benzyliden)-aniline 
• 22543-77-7 (2,6-dichlorophenyl)(phenyl)methanol 
• 104669-26-3 (2,6-dichlorobenzylidene)aniline 
• 68828-00-2 14-(2,6-dichlorophenyl)-14H-dibenzo[a,j]xanthene 
• 2972-79-4 2-(2,6-dichlorobenzylidene)malononitrile 
• 15258-73-8 2,6-dichlorobenzyl alcohol 
• 59714-30-6 2,6-dichlorobenzaldehyde hydrazone 
• 25185-95-9 2,6-dichlorobenzaldoxime 

Relevant articles and documents

Self-assembled nanoporphyrins in the presence of gold bio-nanoparticles as heterogeneous nano-biocatalyst for green production of aldehydes and ketones

We report a simple and facile self-assembly method for the successful fabrication of a biological macromolecule, MnTPPCl (manganese(III) chloride 5,10,15,20-tetraphenylporphyrin), intercalated into gold nanoparticles using the cooperative effects of Sesbania sesban plant. This biohybrid was characterized using various techniques for further investigation. The catalytic activity of this biological hybrid was considered in the production of aldehydes and ketones from primary and secondary alcohols, respectively. Excellent conversions and selectivties were obtained applying Au@MnTPPCl colloidal nanocomposite and NaIO4 as an oxygen donor in ethanol.

A tunable synthesis of either benzaldehyde or benzoic acid through blue-violet LED irradiation using TBATB

In this paper, a highly efficient, metal-free, and homogeneous method for the selective aerobic photooxidation of alcohols and photooxidative-desilylation of tert-butyldimethylsilyl ethers (TBDMS) in the presence of tetrabutylammonium tribromide (TBATB) under irradiation of visible light was reported. The light source: blue (460 nm) and violet (400 nm) LED, can control selective oxidation to aldehyde or carboxylic acid.

Visible-light assisted of nano Ni/g-C3N4 with efficient photocatalytic activity and stability for selective aerobic C?H activation and epoxidation

A selective, economical, and ecological protocol has been described for the oxidation of methyl arenes and their analogs to the corresponding carbonyl compounds and epoxidation reactions of alkenes with molecular oxygen (O2) or air as a green oxygen source, under mild reaction conditions. The nano Ni/g-C3N4 exhibited high photocatalytic activity, stability, and selectivity in the C?H activation of methyl arenes, methylene arenes, and epoxidation of various alkenes under visible- light irradiation without the use of an oxidizing agent and under base free conditions.