1289404-73-4Relevant academic research and scientific papers
Trichloropyruvate N-acylimines. reactions with phosphorus nucleophiles
Khomutnik, Ya. Ya.,Onys'Ko, P. P.,Rassukanaya, Yu. V.,Vlasenko, A. G.,Chernega, A. N.,Brovarets, V. S.,Pil'O, S. G.,Sinitsa, A. D.
, p. 1058 - 1064,7 (2020/08/31)
Reactions of N-aroyltrichloroethaneimines CCl3C(R)=NCOAr (II, R = COOMe, CN) with phosphorus nucleophiles were studied. The reaction of imines II with o-phenylenediethylamidophosphite proceeded as [4+1]-cycloaddition leading to formation of stable spirocy
Novel synthetic approach for N-acyl imines of trichloropyruvate
Onys'ko, Petro P.,Khomutnyk, Yaroslav Y.,Kim, Tetyana V.,Kyselyova, Olena I.,Rassukana, Yuliya V.,Brovarets, Volodymyr S.,Synytsya, Anatoly D.
experimental part, p. 65 - 68 (2011/02/24)
A convenient synthesis for N-acyl imines of trichloropyruvates [2-(acylimino)-3,3,3-trichloropropanoates] based on consecutive silylation-chlorinative desilylation of readily accessible α-(acylamino)- substituted dichloroacrylates was developed. The use o
