128951-86-0Relevant academic research and scientific papers
Solid-state organometallic chemistry of tripodal (polyphosphine)metal complexes. C-H activation reactions at cobalt(I) encapsulated into the tetraphosphine P(CH2CH2PPh2)3
Bianchini, Claudio,Peruzzini, Maurizio,Zanobini, Fabrizio
, p. 3415 - 3417 (2008/10/08)
The solid-vapor reactions of [(PP3)Co(N2)]-BPh4 with HC≡HC, H2C=CH2, CH2O, MeCHO, and CO are described (PP3 = P(CH2CH2PPh2)3). The organic molecules either displace N2, forming a 1:1 complex, or undergo C-H bond cleavage at cobalt to give intermediates that may optionally eliminate H2 or promote hydrogen transfer from metal to coordinated organic ligand.
