136379-88-9

Upstream product

• 128951-86-0 {P(CH₂CH₂P(C₆H₅)2)3}Co(N₂)⁽¹⁺⁾*B(C₆H₅)4^(1-)={P(CH₂CH₂P(C₆H₅)2)3Co(N₂)}B(C₆H₅)4 
• 74-85-1 ethene 

Downstream Products

• 128951-86-0 {P(CH₂CH₂P(C₆H₅)2)3}Co(N₂)⁽¹⁺⁾*B(C₆H₅)4^(1-)={P(CH₂CH₂P(C₆H₅)2)3Co(N₂)}B(C₆H₅)4 

Relevant academic research and scientific papers

Solid-state organometallic chemistry of tripodal (polyphosphine)metal complexes. C-H activation reactions at cobalt(I) encapsulated into the tetraphosphine P(CH2CH2PPh2)3

The solid-vapor reactions of [(PP3)Co(N2)]-BPh4 with HC≡HC, H2C=CH2, CH2O, MeCHO, and CO are described (PP3 = P(CH2CH2PPh2)3). The organic molecules either displace N2, forming a 1:1 complex, or undergo C-H bond cleavage at cobalt to give intermediates that may optionally eliminate H2 or promote hydrogen transfer from metal to coordinated organic ligand.