128970-26-3Relevant academic research and scientific papers
Chemical labeling strategy with (R)- and (S)-trifluoromethylalanine for solid state 19F NMR analysis of peptaibols in membranes
Maisch, Daniel,Wadhwani, Parvesh,Afonin, Sergii,Boettcher, Christoph,Koksch, Beate,Ulrich, Anne S.
supporting information; experimental part, p. 15596 - 15597 (2010/01/30)
(Figure Presented) Substitution of a single Aib-residue in a peptaibol with (R)- and (S)-trifluoromethylalanine yields two local orientational constraints θ by solid state 19F NMR. The structure of the membrane-perturbing antibiotic alamethicin
Fluorine-containing α-alkynyl amino esters and access to a new family of 3,4-dehydroproline analogues
Semeril,Le Notre,Bruneau,Dixneuf,Kolomiets,Osipov
, p. 16 - 18 (2007/10/03)
New α-alkynyl, α-CF3 amino esters have been prepared from electrophilic imines and used to produce 3-alkenyl-3,4-dehydroproline derivatives, via enyne metathesis with the precatalyst [Ru=C=C=CPh2(Cl)(PCy3)(arene)]O3/
Synthesis of Optically Pure (R)- and (S)-α-Trifluoromethyl-Alanine
Bravo, Pierfrancesco,Capelli, Silvia,Meille, Stefano Valdo,Viani, Fiorenza,Zanda, Matteo,et al.
, p. 2009 - 2018 (2007/10/02)
(+)-R- and (-)-(S)-3,3,3-trifluoro-2-methyl-alanine (1) were synthesized from (+)-(R)-methyl-p-tolylsulphoxide (5) and N-alkoxycarbonylimino derivatives 4 of methyl 3,3,3-trifluoropyruvate (3).The absolute configuration was determined by X-ray analyses of
New Synthetic Pathways to 3,3,3-Trifluoroalanine, 2-Deutero-3,3,3-trifluoroalanine and their Derivatives
Burger, Klaus,Hoess, Eva,Gaa, Karl,Sewald, Norbert,Schierlinger, Christian
, p. 361 - 384 (2007/10/02)
New synthetic pathways to 3,3,3-trifluoroalanine, 2-deutero-3,3,3-trifluoroalanine, their esters, amides, and thioamides are described, starting from hexafluoroacetone, and trifluoropyruvates, respectively.
