128971-07-3

Basic information

• Product Name: 4-[4-(2,5-Bis-trifluoromethyl-phenyl)-buta-1,3-diynyl]-phenylamine
• CAS NO: 128971-07-3
• Molecular Weight: 353.267
• Mol File: 128971-07-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 4-[4-(2,5-Bis-trifluoromethyl-phenyl)-buta-1,3-diynyl]-phenylamine(CAS DataBase Reference)
• NIST Chemistry Reference: 4-[4-(2,5-Bis-trifluoromethyl-phenyl)-buta-1,3-diynyl]-phenylamine(128971-07-3)
• EPA Substance Registry System: 4-[4-(2,5-Bis-trifluoromethyl-phenyl)-buta-1,3-diynyl]-phenylamine(128971-07-3)

Safety Data

• Hazardous Substances Data: 128971-07-3(Hazardous Substances Data)

Upstream product

• 328-92-7 2-iodo-1,4-bis-(trifluoromethyl)-benzene 
• 91511-84-1 p-(5-methyl-5-hydroxy-1,3-hexadiynyl)aniline 
• 14235-81-5 4-Ethynylaniline 

Relevant articles and documents

PREPARATION AND NONLINEAR OPTICAL PROPERTY OF POLYDIACETYLENES FROM UNSYMMETRICAL DIPHENYLBUTADIYNES WITH TRIFLUOROMETHYL SUBSTITUENTS

In order to obtain the polydiacetylenes having ?-conjugation between polymer backbone and side chains, many of unsymmetrical diphenylbutadiyne derivatives with trifluoromethyl substituents on one of the phenyl rings have been synthesized.Among them, 1-(3-(methylamino)phenyl)-4-(3,5-bis(trifluoromethyl)phenyl)butadiyne (MADF) was found to be topochemically polymerized with complete conversion into the polymer single crystals.Spectroscopies and X-ray crystal structure analysis revealed that the ?-conjugation of this polymer are more extended than those of the sofar prepared poly(diphenylbutadiyne)s, with smaller dihedral angles between ?-conjugation planes of polymer backbone and phenyl rings.The extended ?-conjugation was also confirmed by larger χ(3) values.