1290029-64-9Relevant academic research and scientific papers
Palladium-catalyzed annulation of diarylamines with olefins through C-H activation: Direct access to N-arylindoles
Sharma, Upendra,Kancherla, Rajesh,Naveen, Togati,Agasti, Soumitra,Maiti, Debabrata
supporting information, p. 11895 - 11899 (2015/01/09)
A palladium-catalyzed dehydrogenative coupling between diarylamines and olefins has been discovered for the synthesis of substituted indoles. This intermolecular annulation approach incorporates readily available olefins for the first time and obviates the need of any additional directing group. An ortho palladation, olefin coordination, and β-migratory insertion sequence has been proposed for the generation of olefinated intermediate, which is found to produce the expected indole moiety.
O -amino conjugation effect on the photochemistry of trans -aminostilbenes
Lin, Cheng-Kai,Prabhakar,Yang, Jye-Shane
, p. 3233 - 3242 (2011/06/10)
The excited-state behavior of a series of trans-2-(N-arylamino)stilbenes (aryl = phenyl (o1H), 4-methylphenyl (o1Me), 4-methoxyphenyl (o1OM), and 4-cyanophenyl (o1CN)) and trans-2-(N,N-diphenylamino)stilbene (o2) in both nonpolar and polar solvents is rep
