1290137-33-5Relevant academic research and scientific papers
Oxygenation of sulfides catalysed by SBA-15-immobilized molybdenum(VI) complex of a bis(phenol) diamine ligand using aqueous hydrogen peroxide as a green oxidant
Saberikia, Iraj,Safaei, Elham,Karimi, Babak,Lee, Yong-Iii
, (2018)
A highly efficient and reusable molybdenum-based catalyst has been synthesized by covalent grafting of a bis(phenol) diamine ligand, namely 2-(((2-bromoethyl)(2-((3,5-di-tert-butyl-2-hydroxybenzyl)amino)ethyl)amino)methyl)-4,6-di-tert-butylphenol, onto functionalized ordered mesoporous silica (SBA-15) followed by complexation with MoO2(acac)2. The resulting organic–inorganic hybrid material was found to be a highly effective catalyst for oxygenation of various sulfides to their corresponding sulfoxides or sulfones. The catalyst was characterized using transmission and scanning electron microscopies, X-ray photoelectron, Fourier transform infrared and atomic absorption spectroscopies, Brunauer–Emmett–Teller surface area analysis and thermogravimetric analysis. Mild reaction conditions, high selectivity and easy recovery and reusability of the catalyst render the presented protocol very useful for addressing industrial needs and environmental concerns.
Synthesis and characterization of two binuclear iron(III) complexes of aminoethanol derivatives of aminophenol as models for non-heme iron enzymes active sites
Safaei, Elham,Saberikia, Iraj,Wojtczak, Andrzej,Jagli?i?, Zvonko,Kozakiewicz, Anna
, p. 1143 - 1148 (2011)
Two aminoethanol derivatives of aminophenol ligands were synthesized and characterized by IR and 1H NMR spectroscopies. The binuclear iron(III) complexes of these ligands have been prepared and characterized by IR, 1H NMR and UV-Vis
