129046-83-9Relevant academic research and scientific papers
N,O-bis(diphenylphosphinoyl)hydroxylamine base-induced rearrangement to a phosphonamidic-phosphinic mixed anhydride
Harger
, p. 1451 - 1454 (2007/10/02)
The hydroxylamine derivative Ph2P(O)NHOP(O)Ph2 rearranges on treatment with Bu(t)OK-Bu(t)OH; the product contains two dissimilar P atoms (δ(p) 24.2 and 7.9, J(pp) 34 Hz) and is rapidly hydrolysed to a phosphonamidate and a phosphinate, consistent with it being the mixed anhydride Ph(PhNH)P(O)OP(O)Ph2.
Rearrangement Reactions of N-Phosphinoyl-O-sulphonylhydroxylamines with Amines under Competitive Conditions. Possible Involvement of Monomeric Metaphosphonimidates and Phosphonamidic Sulphonic Mixed Anhydrides
Harger, Martin J. P.,Smith, Adrian
, p. 2507 - 2511 (2007/10/02)
The O-methylsulphonyl-N-phosphinoylhydroxylamines, RPhP(O)NHOMs (R=Ph, Me, Et, Pri), react with an excess of an equimolar mixture of isopropylamine and t-butylamine to give the rearrangement products RP(O)(NHPh)(NHPri) and RP(O)(NHPh
