129062-15-3

Upstream product

• 91190-38-4 N-benzyl-1,2-O-isopropylidene-D-glyceraldehyde nitrone 
• 292638-85-8 acrylic acid methyl ester 
• 67-64-1 acetone 
• 455942-10-6 (3S,5S)-2-benzyl-3-(1,4-dioxa-spiro[4,5]dec-2-yl)isoxazolidine-5-carboxylic acid methyl ester 
• 91190-38-4 N-benzyl-2,3-O-isopropylidene-D-glyceraldehyde nitrone 
• 622-30-0 N-benzyl hydroxylalmine 

Downstream Products

• 455942-25-3 (3S,5S)-5-[(4S)-2,2-dimethyl-1,3-dioxolan-4-yl]-3-(benzoyloxy)-2-oxo-pyrrolidine-1-carboxylic acid tert-butyl ester 
• 455942-22-0 benzoic acid (3S,5S)-5-[(4S)-2,2-dimethyl-1,3-dioxolan-4-yl]-2-oxo-pyrrolidin-3-yl ester 
• 455942-19-5 (3S,5S)-2-benzyl-3-formyl-isoxazolidine-5-carboxylic acid methyl ester 
• 455942-29-7 (3S,5S)-2-benzyl-3-[(1S)-1,2-dihydroxy-ethyl]-isoxazolidine-5-carboxylic acid methyl ester 
• 455942-36-6 acetic acid (3S,5S)-1-benzyl-5-[(4S)-2,2-dimethyl-1,3-dioxolan-4-yl]-2-oxo-pyrrolidin-3-yl ester 

Relevant academic research and scientific papers

Experimental and theoretical study of the 1,3-dipolar cycloaddition between D-glyceraldehyde nitrones and acrylates. Diastereoselective approach to 4-hydroxy pyroglutamic acid derivatives

The 1,3-dipolar cycloaddition reactions of five D-glyceraldehyde nitrones with alkyl acrylates and Oppolzer's sultam acrylamide have been studied in detail, the study including double chiral induction experiments. A complete theoretical study of the react

Structure, Synthesis and Absolute Configuration of Leptosphaerin, a Metabolite of the Marine Ascomycete Leptosphaeria oraemaris.

A structure 3 erroneously deduced for the marine fungal metabolite leptosphaerin on the basis of spectroscopic evidence and an ambiguous x-ray analysis was disproved by synthesis.An alternative formulation 1, including its absolute configuration, was conf

THE STRUCTURE OF LEPTOSPHAERIN

The structure and relative configuration of leptosphaerin, a metabolite of the marine ascomycete Leptophaeria oraemaris (Linder) was established as 2 by spectral analysis and elimination of an alternative structure 1 through synthesis.