129076-06-8Relevant academic research and scientific papers
A palladium-catalyst stabilized in the chiral environment of a monoclonal antibody in water
Kobayashi, Yuichiro,Murata, Keisuke,Harada, Akira,Yamaguchi, Hiroyasu
, p. 1605 - 1607 (2020)
We report the first preparation of a monoclonal antibody (mAb) that can immobilize a palladium (Pd)-complex. The allylic amination reaction using a supramolecular catalyst consisting of the Pd-complex and mAb selectively gives the (R)-enantiomer product w
Amphiphilic π-Allyliridium C,O-Benzoates Enable Regio- and Enantioselective Amination of Branched Allylic Acetates Bearing Linear Alkyl Groups
Meza, Arismel Tena,Wurm, Thomas,Smith, Lewis,Kim, Seung Wook,Zbieg, Jason R.,Stivala, Craig E.,Krische, Michael J.
supporting information, p. 1275 - 1279 (2018/02/09)
The first examples of amphiphilic reactivity in the context of enantioselective catalysis are described. Commercially available π-allyliridium C,O-benzoates, which are stable to air, water and SiO2 chromatography, and are well-known to catalyze
Asymmetric allylic amination catalyzed by chiral ferrocenylphosphine-palladium complexes
Hayashi, Tamio,Kishi, Kohei,Yamamoto, Akihiro,Ito, Yoshihiko
, p. 1743 - 1746 (2007/10/02)
A palladium complex bearing chiral (hydroxyalkyl)ferrocenylphosphine ligand was found to be a highly regio-and stereoselective catalyst for the asymmetric allylic animation of 2-butenyl acetates with benzylamine, the nucleophilic attack of the amine takin
