1291054-56-2Relevant academic research and scientific papers
Highly efficient large bite angle diphosphine substituted molybdenum catalyst for hydrosilylation
Chakraborty, Subrata,Blacque, Olivier,Fox, Thomas,Berke, Heinz
, p. 2208 - 2217 (2013)
Treatment of the complex Mo(NO)Cl3(NCMe)2 with the large bite angle diphosphine, 2,2′-bis(diphenylphosphino)diphenylether (DPEphos) afforded the dinuclear species [Mo(NO)(PaP)Cl 2]2[μCl]2 (PaP = DPEph
Role of low-valent rhenium species in catalytic hydrosilylation reactions with oxorhenium catalysts
Smeltz, Jessica L.,Boyle, Paul D.,Ison, Elon A.
, p. 5994 - 5997 (2012/10/30)
The catalytic competency of a Re(III) complex has been demonstrated. In the presence of silane, oxorhenium(V) catalysts are deoxygenated to produce species that are significantly more active than the metal oxo precursors in hydrosilylation reactions. The results presented suggest that, in evaluating mechanisms for catalytic hydrosilylation reactions that involve high-valent metal oxo complexes, the activity of species that may be generated by deoxygenation of the metal with silane should also be systematically investigated as potential catalysts.
