129108-73-2Relevant academic research and scientific papers
Photocyclization of (ω-Dialkylamino)alkyl β-Oxoesters via Remote Hydrogen Transfer
Hasegawa, Tadashi,Ogawa, Takuya,Miyata, Kazuko,Karakizawa, Atsushi,Komiyama, Mikiko,et al.
, p. 901 - 905 (2007/10/02)
The (ω-dialkylamino)alkyl β-oxoesters (1) undergo photocyclization via remote hydrogen transfer to give the medium-sized azalactones (2) and/or aminolactones (3).Intramolecular electron transfer from nitrogen to the excited carbonyl group of (1) occurs prior to the remote hydrogen transfer.
