1291100-05-4Relevant academic research and scientific papers
Enantiopure 1,4-diols and 1,4-aminoalcohols via stereoselective acyclic sulfoxide-sulfenate rearrangement
Fernandez De La Pradilla, Roberto,Colomer, Ignacio,Urena, Mercedes,Viso, Alma
, p. 2468 - 2471 (2011)
Chemical equations presented. Treatment of acyclic α-hydroxy and α-tosylamino sulfinyl dienes with amines affords enantiopure 1,4-diol or 1,4-hydroxysulfonamide derivatives in good yields and diastereoselectivities. This one-pot procedure entails a conjugate addition that triggers a diastereoselective sulfoxide-sulfenate [2,3]-sigmatropic rearrangement.
Sulfinyl-Mediated Stereoselective Functionalization of Acyclic Conjugated Dienes
Colomer, Ignacio,Ure?a, Mercedes,Viso, Alma,Fernández de la Pradilla, Roberto
supporting information, p. 4620 - 4632 (2020/04/09)
The chemo- and stereocontrolled functionalization of conjugated sulfinyl dienes in a cascade process that involves a conjugate addition, diastereoselective protonation and a [2,3]-sigmatropic rearrangement is reported. Enantioenriched 1,4-diol and 1,4-ami
