1291103-55-3Relevant articles and documents
Copper-catalyzed enantioselective propargylic amination of nonaromatic propargylic esters with amines
Yoshida, Akiko,Hattori, Gaku,Miyake, Yoshihiro,Nishibayashi, Yoshiaki
supporting information; experimental part, p. 2460 - 2463 (2011/07/09)
Chemical equations presented. The enantioselective propargylic amination of propargylic pentafluorobenzoates bearing an alkyl group at the propargylic position with amines in the presence of catalytic amounts of a copper complex and an optically active diphosphine such as BINAP has been found to give the corresponding propargylic amines in good yields with high enantioselectivity.