1291103-72-4Relevant academic research and scientific papers
Chiral tridentate P,N,N ligands for highly enantioselective copper-catalyzed propargylic amination with both primary and secondary amines as nucleophiles
Zhang, Cheng,Wang, Ya-Hui,Hu, Xin-Hu,Zheng, Zhuo,Xu, Jie,Hu, Xiang-Ping
supporting information, p. 2854 - 2858 (2013/01/15)
Chiral tridentate P,N,N ligands have been demonstrated to be highly efficient for the coppercatalyzed enantioselective propargylic amination of propargylic acetates with both primary and secondary amines as nucleophiles, affording the corresponding propar
Copper-catalyzed enantioselective propargylic amination of nonaromatic propargylic esters with amines
Yoshida, Akiko,Hattori, Gaku,Miyake, Yoshihiro,Nishibayashi, Yoshiaki
, p. 2460 - 2463 (2011/07/09)
Chemical equations presented. The enantioselective propargylic amination of propargylic pentafluorobenzoates bearing an alkyl group at the propargylic position with amines in the presence of catalytic amounts of a copper complex and an optically active diphosphine such as BINAP has been found to give the corresponding propargylic amines in good yields with high enantioselectivity.
