129152-14-3Relevant academic research and scientific papers
Radical-induced epoxide fragmentation chemistry. Atom transfer cyclization of iodoepoxides to cyclopentanols
Rawal,Iwasa
, p. 4687 - 4690 (2007/10/02)
Iodoepoxides, formed by the reaction of PhI(OAc)2 and I2 with an allylic alcohol, can be rearranged to cis-fused bicyclic compounds using catalytic amounts of (n-Bu3Sn)2 and AIBN. Formally an atom transfer cycli
Synthesis of Carbocyclic Systems via Radical-Induced Epoxide Fragmentation
Rawal, Viresh H.,Newton, Randall C.,Krishnamurthy, Venkat
, p. 5181 - 5183 (2007/10/02)
Cis-fused bicyclic compounds are synthesized from simple monocyclic enone precursors.The key step involves a tandem radical-mediated epoxide fragmentation, radical translocation, and cyclization.
