144730-06-3Relevant academic research and scientific papers
Stereoselective radical cyclization of epoxy silyl enol ethers
Kim,Koh
, p. 7391 - 7392 (1992)
n-Bu3Sn radical catalyzed stereoselective radical cyclization of epoxy silyl enol ethers is described.
Radical Cyclization of Epoxyketones via a 1,5-Bun3Sn Group or a 1,5-H Atom Transfer
Kim, Sunggak,Koh, Jae Suk
, p. 1377 - 1378 (2007/10/02)
Radical cyclization of epoxyketones is initited by Bun3Sn radical addition to epoxyketones, followed by epoxide fragmentation, 1,5-H- or 1,5-Bun3Sn transfer, and cyclization.
Synthesis of Carbocyclic Systems via Radical-Induced Epoxide Fragmentation
Rawal, Viresh H.,Newton, Randall C.,Krishnamurthy, Venkat
, p. 5181 - 5183 (2007/10/02)
Cis-fused bicyclic compounds are synthesized from simple monocyclic enone precursors.The key step involves a tandem radical-mediated epoxide fragmentation, radical translocation, and cyclization.
