129170-93-0

Upstream product

• 3162-96-7 methyl 4,6-O-benzylidene-α-D-glucopyranoside 
• 7177-79-9 methyl 2,3-di-O-benzyl-4,6-O-benzylidene-α-D-glucopyranoside 
• 100-39-0 benzyl bromide 
• 17791-36-5 methyl 2,3-di-O-benzyl-α-D-glucopyranoside 
• 3162-96-7 4,6-O-benzylidene-1-O-methyl-α-D-glucopyranoside 
• 97-30-3 methyl-alpha-D-glucopyranoside 
• 129077-21-0 methyl 2,3-di-O-benzyl-6-bromo-6-deoxy-α-D-glucopyranoside 
• 100-46-9 benzylamine 
• 7177-79-9 methyl 2,3-O-dibenzyl-4,6-O-benzylidene-α-D-glucopyranoside 

Downstream Products

• 129077-30-1 (R)-1-((2S,3S,4S)-1-Benzyl-3,4-bis-benzyloxy-pyrrolidin-2-yl)-ethane-1,2-diol 
• 129077-31-2 (S)-1-((2S,3S,4S)-1-Benzyl-3,4-bis-benzyloxy-pyrrolidin-2-yl)-ethane-1,2-diol 
• 273720-69-7 N-benzyl-2,3-di-O-benzyl-1,5,6-trideoxy-1,5-imino-D-gluco-heptitol 
• 273720-70-0 N-benzyl-2,3-di-O-benzyl-1,5,6-trideoxy-1,5-imino-L-ido-heptitol 
• 273720-68-6 N-benzyl-2,3-di-O-benzyl-6-chloro-1,5,6-trideoxy-1,5-imino-L-iditol 
• 273720-66-4 3,7-anhydro-2,7-dideoxy-N-benzyl-5,6-di-O-benzyl-3,7-imino-L-ido-1,4-heptonolactone 
• 273720-65-3 3,7-anhydro-2,7-dideoxy-N-benzyl-5,6-di-O-benzyl-3,7-imino-L-gulo-1,4-heptonolactone 
• 129077-22-1 (2S,3S,4S)-1-Benzyl-3,4-bis-benzyloxy-2-vinyl-pyrrolidine 

Relevant academic research and scientific papers

Pd(II)-catalysed aminocarbonylation as a key step in the total synthesis of C-6 homologues of 1-deoxynojirimycin and 1-deoxy-L-idonojirimycin

The first successful Pd(II)-catalysed aminocarbonylation of the highly substituted benzylaminoalkene 5 allows the direct preparation of fused piperidine lactones 3 and 4, which are subsequently converted to the novel C-6 homologue of 1-deoxynojirimycin 1

Total synthesis of new C-6 homologues of 1-deoxynojirimycin and 1-deoxy- L-idonojirimycin

Novel piperidine lactones 1 and 2, which represent direct precursors to the new C-6 homologues of 1-deoxynojirimycin (3) and 1-deoxy-L-donojirimycin 4, were prepared by key Pd(II)-catalysed aminocarbonylation of protected aminoalkene 10.

A SHORT, VERSATILE APPROACH TO POLYHYDROXYLATED PYRROLIDINES UTILIZING A REDUCTIVE ELIMINATION-REDUCTIVE AMINATION AS A KEY STEP

An efficient synthesis of epimeric alpha-vinyl pyrrolidines starting from methyl 4,6-O-benzyliden gluco- and galactopyranosides gave ready access to hydroxylated pyrrolidines.