129196-82-3

Basic information

• Product Name: 3-(2-FURYL)-N-PHENYLACRYLAMIDE
• Synonyms: 3-(2-FURYL)-N-PHENYLACRYLAMIDE
• CAS NO: 129196-82-3
• Molecular Formula: C₁₃H₁₁NO₂
• Molecular Weight: 213.23
• Mol File: 129196-82-3.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 410.9±37.0 °C(Predicted)
• Appearance: /
• Density: 1.224±0.06 g/cm3(Predicted)
• PKA: 12.95±0.70(Predicted)
• CAS DataBase Reference: 3-(2-FURYL)-N-PHENYLACRYLAMIDE(CAS DataBase Reference)
• NIST Chemistry Reference: 3-(2-FURYL)-N-PHENYLACRYLAMIDE(129196-82-3)
• EPA Substance Registry System: 3-(2-FURYL)-N-PHENYLACRYLAMIDE(129196-82-3)

Safety Data

• Hazardous Substances Data: 129196-82-3(Hazardous Substances Data)

Upstream product

• 67998-15-6 (E)-3-(furan-2-yl)acrylic anhydride 
• 62-53-3 aniline 
• 1487-18-9 (furan-2-yl)ethylene 
• 103-71-9 phenyl isocyanate 
• 20689-54-7 (E)-3-(2-furyl)acryloyl chloride 
• 539-47-9 3-(fur-2-yl)crotonic acid 
• 98-00-0 (2-furyl)methyl alcohol 
• 103-84-4 Acetanilid 

Relevant articles and documents

Diastereoselective Diels-Alder Reaction of 2-Thienyl and 2-Furyl Substituted 3-Propenethioamides with Electron Deficient Dienophiles

The hetero-Diels-Alder reaction of N-aryl-3-(2-thienyl)-2- propenethioamides with N-phenylmaleimide and maleimide yielded a mixture of endo- and exo-2-arylimino-4-(2-thienyl)tetrahydrothiopyran[2,3-c]pyrroles. Cycloaddition to diethyl fumarate required acylation and furnished a mixture of diastereoisomeric 5-(N-acetylphenylamino)-2,3-bis-(ethoxycarbonyl)-4-(2-thienyl) -3,4-dihydro-2H-thiopyrans. Reactions of 3-(2-furyl)-2-propenethioamides with N-arylmaleimides furnished the correspondent 2-arylimino-4-(2-furyl) tetrahydrothiopyran[2,3-c]pyrroles. In the cycloadditions of the heterodienes with N-arylmaleimides the endo-cycloadducts were formed as the major products.

Nickel(0) induzierte und katalysierte CC-Verknuepfungen zwischen Phenylisocyanat und vinylsubstituierten Heteroaromaten

Vinyl substituted heterocycles such as 2-vinylfuran (Ia) and 2-vinylpyridine (Ib) react with phenylisocyanate (II) in presence of (Lig)Ni0 (Lig = TCP) to form the tricyclohexylphosphane-5-azanickelacyclopentan-4-one derivatives (V).The structures and properties of these metallacycles are described.A catalytic 1/1 CC bond formation to give the α,β-unsaturated carboxylic acid amide X proceeds only with Ia (Lig = P(OiP)3) and not with Ib (Lig = PEt3, PPh3, P(OiP)3).Presumably, the different reactivities are not caused by electronic and/or steric factors of the 2-furyl- or 2-pyridyl-substituents, but by the donor properties of the N-atom in Ib.The N Ni interactions in the complex bis2-2-vinyl-μ-pyridine-nickel> (XIIb) can be detected by spectroscopic and crystal structure studies.