Welcome to LookChem.com Sign In|Join Free
  • or

98-00-0

Post Buying Request

98-00-0 Suppliers

Recommended suppliersmore

Product FOB Price Min.Order Supply Ability Supplier
Furfuryl alcohol, 98% Furfuryl Alcohol buy, Good quality Furfuryl alcohol 98%,Furfuryl alcohol price
Cas No: 98-00-0
No Data 1000 Kilogram 1000 Metric Ton/Day Shandong Xinhua Pharmaceutical Co.,Ltd Contact Supplier
Factory Supply Furfuryl Alcohol
Cas No: 98-00-0
No Data 1 1 Ality Chemical Corporation Contact Supplier
Furfuryl Alcohol
Cas No: 98-00-0
No Data No Data No Data Aecochem Corp. Contact Supplier
Furfuryl alcohol
Cas No: 98-00-0
No Data 1 Kilogram 30 Metric Ton/Month Simagchem Corporation Contact Supplier
Furfuryl alcohol CAS 98-00-0
Cas No: 98-00-0
No Data 1 Metric Ton 10 Metric Ton/Day Hefei TNJ chemical industry co.,ltd Contact Supplier
2-furanylmethanol
Cas No: 98-00-0
No Data 10 Milligram Amadis Chemical Co., Ltd. Contact Supplier
Furfuryl alcohol
Cas No: 98-00-0
No Data No Data No Data Chemwill Asia Co., Ltd. Contact Supplier
2016 hot sale Furfuryl alcohol,98-00-0
Cas No: 98-00-0
USD $ 1.0-2.0 / Metric Ton 5 Metric Ton 30 Metric Ton/Day Henan Sinotech Import&Export Corporation Contact Supplier
Furfuryl alcohol Manufacturer/High quality/Best price/In stock
Cas No: 98-00-0
USD $ 3.0-3.0 / Kilogram 1 Kilogram 1-100 Metric Ton/Month Dayang Chem (Hangzhou) Co.,Ltd. Contact Supplier
Furfuryl alcohol
Cas No: 98-00-0
USD $ 500.0-500.0 / Gram 1000 Gram 10 Metric Ton/Month Hebei yanxi chemical co.,LTD. Contact Supplier

98-00-0 Usage

Environmental fate

Biological. In activated sludge inoculum, following a 20-d adaptation period, 97.3% COD removal was achieved. The average rate of biodegradation was 41.0 mg COD/g?h (Pitter, 1976). Chemical/Physical. Easily resinified by acids (Windholz et al., 1983). Furfuryl alcohol will not hydrolyze because it has no hydrolyzable functional group. In barrel-aged red, white, and model wines, naturally occurring furfuryl alcohol decreased in concentration with time. In red wine, furfuryl ethyl ether was identified as a degradation product after 55 wk of storage. The average percentage decrease of furfuryl alcohol was 73% (Spillman et al., 1998).

General Description

A clear colorless liquid. Flash point 167°F. Boiling point 171°F. Denser than water. Contact may irritate skin, eyes and mucous membranes. May be toxic by ingestion and skin contact and moderately toxic by inhalation.

Purification Methods

Distil it under reduced pressure to remove tarry material, shake with aqueous NaHCO3, dry it with Na2SO4 and fractionally distil it under reduced pressure from Na2CO3. It can be further dried by shaking with Linde 5A molecular sieves. [Beilstein 17/3 V 338.]

Uses

Furfuryl Alcohol has been obtained by yeast reduction of furfural. Furfuryl Alcohol is used as solvent and in the manufacturing of wetting agents, resins.

Carcinogenicity

The NTP conducted a 2-year inhalation study on furfuryl alcohol. F344 rats and B6C3F1 mice were exposed to 0, 2, 8, or 32 ppm furfuryl alcohol for 6 h/day, 5 days/week. All rats exposed to 32 ppm died by week 99; survival of all other animals was similar to control animals. There were increased incidences of nasal tumors in the male rats and increased incidences of kidney tubule tumors in male mice. Increased incidences of nonneoplastic lesions of the nose and increased severities of nephropathy were observed in male and female rats and male mice. Nonneoplastic lesions of nose and corneal degeneration occurred in female mice.

Description

Furfuryl alcohol is clear colorless organic liquid having a furan substituted with a hydroxymethyl group. It is primarily used for the synthesis of furans resins which are used in thermoset polymer matrix composites, cements, adhesive and coatings. It plays an essential role in the production of foundry sand binder and has long been used to produce cores and molds for metal casting. Other applications include as a fuel and wood treatment. In industry, it is manufactured through either direct reduction of furfural, or through the disproportionation via the Cannizaro reaction in NaOH solution. The basic raw materials for its manufacturing are waste vegetable materials such as rice hulls, sugar cane bagasse, oat hulls or corncobs.

Occurrence

Reported found in roasted almonds, cooked apple, apple juice, roasted barley, beans, beef fat, canned beef stew, beer, brandy, white bread, cocoa, cocoa bean, roasted coffee, roasted flberts, honey, heated skim milk, dried mushrooms, roasted onion, yellow passion fruit, roasted peanuts, pineapple, popcorn, potato chips, roasted sesame seeds, cheeses, milk, meats, grape wines, cognac, whiskies, soybean products, coconut, corn oil, shrimps, clams and other sources

Chemical Properties

clear yellow liquid

Physical properties

Clear, colorless to pale yellow liquid with an irritating odor. Darkens to yellowish-brown on exposure to air. A detection odor threshold concentration of 32 mg/m3 (8.0 ppmv) was determined by Jacobson et al. (1958).

Potential Exposure

Used as a starting monomer in the production of furan resins and used to produce tetrahydro furfural alcohol (THFA).

Safety Profile

Poison by ingestion, skin contact, and subcutaneous routes.Moderately toxic by inhalation and intraperitoneal routes. Mutation data reported. An eye irritant. Flammable when exposed to heat or flame; can react with oxidtzing materials. Moderate explosion hazard when exposed to heat or flame. Reacts violently with acids (e.g., formic acid, cyanoacetic acid + heat). Ignites on contact with 85% hydrogen peroxide. To fight fire, use alcohol foam, CO2, dry chemical. When heated to decomposition it emits acrid smoke and fumes.

Waste Disposal

Incineration in admixture with a more flammable solvent.

Chemical Properties

Furfuryl alcohol has a very mild, warm, oily, “burnt” odor and a cooked sugar taste.

Fire Hazard

Combustible material: may burn but does not ignite readily. When heated, vapors may form explosive mixtures with air: indoors, outdoors and sewers explosion hazards. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated. Runoff may pollute waterways. Substance may be transported in a molten form.

Air & Water Reactions

Slightly soluble in water.

Hazard

May react explosively with mineral acids and some organic acids. Toxic by inhalation and skin absorption. Approved for food products. Toxic by skin absorption.

Uses

Solvent; manufacture of wetting agents, resins.

Aroma threshold values

Detection: 1 to 2 ppm.

Incompatibilities

Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explo sions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. Contact with acids can cause polymerization. Strong reaction with oxidizers. Incompatible with alkaline earth and alkali metals; strong caustics; aliphatic amines; isocyanates, acetaldehyde, benzoyl peroxide; chromic acid, chromium trioxide; cyanoacetic acid; dialkylzincs, dichlorine oxide; ethylene oxide; hydrogen per oxide; isopropyl chlorocarbonate; lithium tetrahydroalumi nate; nitric acid; nitrogen dioxide; pentafluoroguanidine, phosphorus pentasulfide; tangerine oil; triethylaluminum, trii sobutylaluminum. Attacks some plastics, coatings and rubber.

Health Hazard

Inhalation causes headache, nausea, and irritation of nose and throat. Vapor irritates eyes; liquid causes inflammation and corneal opacity. Contact of skin with liquid causes dryness and irritation. Ingestion causes headache, nausea, and irritation of mouth and stomach.

Definition

ChEBI: A member of the class of furans bearing a hydroxymethyl substituent at the 2-position.

Source

Furfuryl occurs naturally in yarrow, licorice, sesame seeds, clove flowers, and tea leaves (Duke, 1992). Also detected in barrel-aged red, white, and model wines. Concentrations ranged from 3.5 mg/L in white wine after 55 wk of aging to 9.6 mg/L after 11 wk of aging (Spillman et al., 1998). Identified as one of 140 volatile constituents in used soybean oils collected from a processing plant that fried various beef, chicken, and veal products (Takeoka et al., 1996).

Chemical Properties

Furfural alcohol is a colorless to amber liquid that darkens on exposure to light. It has a faint, burning odor.

Shipping

UN2874 Furfuryl alcohol, Hazard Class: 6.1; Labels: 6.1-Poisonous materials.

Uses

Colorless liquid that turns dark in air

Taste threshold values

Taste characteristics at 50 ppm: burnt, sweet, caramellic and brown.

Preparation

Usually prepared from furfural that is obtained by the processing of corncobs; oil obtained by steam distillation of roasted coffee bean meal consists of 50% furfuryl alcohol; prepared industrially by the catalytic reduction of furfural using nickel and Cu-CrO catalysts.

Chemical Reactivity

Reactivity with Water No reaction; Reactivity with Common Materials: No reactions; Stability During Transport: The product darkens and forms water insoluble material on exposure to air or acids. This reaction is accelerated at elevated temperatures; Neutralizing Agents for Acids and Caustics: Not pertinent; Polymerization: Not pertinent; Inhibitor of Polymerization: Not pertinent.

Synthesis Reference(s)

Synthesis, p. 246, 1977Tetrahedron Letters, 33, p. 5417, 1992 DOI: 10.1016/S0040-4039(00)79109-X

References

https://en.wikipedia.org/wiki/Furfuryl_alcohol http://www.furan.com/furfuryl_alcohol_applications.html
InChI:InChI=1/C5H6O2/c6-4-5-2-1-3-7-5/h1-3,6H,4H2

98-00-0 Well-known Company Product Price

Brand (Code)Product description CAS number Packaging Price Detail
Alfa Aesar (A10968)  Furfuryl alcohol, 98%    98-00-0 50g 153.0CNY Detail
Alfa Aesar (A10968)  Furfuryl alcohol, 98%    98-00-0 250g 207.0CNY Detail
Alfa Aesar (A10968)  Furfuryl alcohol, 98%    98-00-0 1000g 566.0CNY Detail
Aldrich (185930)  Furfurylalcohol  98% 98-00-0 185930-50G 239.85CNY Detail
Aldrich (185930)  Furfurylalcohol  98% 98-00-0 185930-250G 360.36CNY Detail
Aldrich (185930)  Furfurylalcohol  98% 98-00-0 185930-1KG 439.92CNY Detail

98-00-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name furfuryl alcohol

1.2 Other means of identification

Product number -
Other names HPFA

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only. Food additives -> Flavoring Agents
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:98-00-0 SDS

98-00-0Synthetic route

furfural
98-01-1

furfural

(2-furyl)methyl alcohol
98-00-0

(2-furyl)methyl alcohol

Conditions
ConditionsYield
With Pt(3)Co(3)/C; hydrogen In water at 35℃; under 750.075 Torr; for 10h; Reagent/catalyst; Pressure; Temperature; Solvent; Concentration;100%
With HRO/TiO2; hydrogen In water at 150℃; under 15001.5 Torr; for 3h;100%
With hydrogen In isopropyl alcohol at 179.84℃; under 22502.3 Torr; for 1.25h; Reagent/catalyst;100%
C20H20BO8(1-)*Na(1+)

C20H20BO8(1-)*Na(1+)

(2-furyl)methyl alcohol
98-00-0

(2-furyl)methyl alcohol

Conditions
ConditionsYield
With water100%
furfural
98-01-1

furfural

A

(2-furyl)methyl alcohol
98-00-0

(2-furyl)methyl alcohol

B

2-furanoic acid
88-14-2

2-furanoic acid

Conditions
ConditionsYield
Stage #1: furfural With potassium hydroxide for 0.0833333h; Cannizzaro Reaction; Milling; Inert atmosphere; Sealed tube; Green chemistry;
Stage #2: With hydrogenchloride In water for 0.0833333h; Green chemistry;
A 99%
B 99%
With TEA; magnesium bromide In dichloromethane at 20℃; for 48h; Cannizzaro reaction;A 90%
B n/a
With sodium hydroxide In water at 0 - 20℃; for 12h; Reagent/catalyst; Cannizzaro Reaction;A 88%
B 83%
2-furoic acid methyl ester
611-13-2

2-furoic acid methyl ester

(2-furyl)methyl alcohol
98-00-0

(2-furyl)methyl alcohol

Conditions
ConditionsYield
With ethanol; [bis({2‐[bis(propan‐2‐yl)phosphanyl]ethyl})amine](borohydride)(carbonyl)(hydride)iron(II) at 100℃; for 24h; Inert atmosphere; Sealed tube; Darkness;99%
With C13H34BFeNOP2; hydrogen In tetrahydrofuran at 100℃; under 22502.3 Torr; for 18h; Autoclave; Inert atmosphere;95%
With [Ru(2-(methylthio)-N-[(pyridin-2-yl)methyl]ethan-1-amine)(triphenylphosphine)Cl2]; potassium tert-butylate; hydrogen In toluene at 80℃; under 37503.8 Torr; for 10h;80%
5-hydroxymethyl-2-furfuraldehyde
67-47-0

5-hydroxymethyl-2-furfuraldehyde

Wilkinson's catalyst
14694-95-2

Wilkinson's catalyst

A

(2-furyl)methyl alcohol
98-00-0

(2-furyl)methyl alcohol

B

chlorocarbonylbis(triphenylphosphine)rhodium(I)
15318-33-9, 16353-77-8, 13938-94-8

chlorocarbonylbis(triphenylphosphine)rhodium(I)

Conditions
ConditionsYield
In further solvent(s) argon-filled glovebox, durene, bibenzyl, heating 24h at 70°C; detn. of products by GC;A 99%
B n/a
In further solvent(s) argon-filled glovebox, durene, bibenzyl, heating 2h at 70°C; detn. of products by GC;A 48%
B n/a
2-(furan-2-ylmethoxy)tetrahydro-2H-pyran
65148-89-2

2-(furan-2-ylmethoxy)tetrahydro-2H-pyran

(2-furyl)methyl alcohol
98-00-0

(2-furyl)methyl alcohol

Conditions
ConditionsYield
With chloral hydrate In hexane at 0 - 5℃; for 0.5h; Inert atmosphere;98%
With methanol; Montmorillonite K-10 clay at 20℃; Methanolytic deprotection;95%
With zinc tetrafluoroborate In methanol; dichloromethane; water at 20℃; for 0.75h;92%
Ethyl 2-furoate
614-99-3

Ethyl 2-furoate

(2-furyl)methyl alcohol
98-00-0

(2-furyl)methyl alcohol

Conditions
ConditionsYield
With C30H34Cl2N2P2Ru; potassium methanolate; hydrogen In tetrahydrofuran at 100℃; under 38002.6 - 76005.1 Torr; for 5h; Glovebox; Autoclave;97%
With ethanol; ruthenium(bis[2‐(ethylsulfanyl)ethyl]amine)(dichloro)(triphenylphosphine); potassium tert-butylate In toluene at 80℃; for 16h;95%
With ethylmagnesium bromide; poly(methylhydrosiloxane); bis(cyclopentadienyl)titanium dichloride In tetrahydrofuran; diethyl ether for 17.5h; Ambient temperature;89%
furfural
98-01-1

furfural

aniline
62-53-3

aniline

A

(2-furyl)methyl alcohol
98-00-0

(2-furyl)methyl alcohol

B

N-(furan-2-ylmethyl)aniline
4439-56-9

N-(furan-2-ylmethyl)aniline

Conditions
ConditionsYield
Stage #1: furfural; aniline at 25℃; for 0.166667h;
Stage #2: With sodium tetrahydroborate; toluene-4-sulfonic acid at 25℃; for 0.166667h;
A n/a
B 97%
With hydrogen; edetate disodium; iron(II) sulfate In water at 150℃; under 20686.5 Torr; for 12h; Title compound not separated from byproducts.;A 7 % Chromat.
B 72 % Chromat.
Stage #1: furfural at 40℃; for 0.166667h;
Stage #2: aniline With sodium tetrahydroborate at 40℃; for 3h;
Stage #3: With methanol at 0℃; for 0.5h; chemoselective reaction;
tert-butyl(furan-2-ylmethoxy)dimethylsilane
121389-55-7

tert-butyl(furan-2-ylmethoxy)dimethylsilane

(2-furyl)methyl alcohol
98-00-0

(2-furyl)methyl alcohol

Conditions
ConditionsYield
With Decaborane In methanol at 20℃; for 0.5h;96%
With sodium hydride In N,N,N,N,N,N-hexamethylphosphoric triamide at 25℃; for 8h;93%
With acetyl chloride In methanol at 20℃; for 0.583333h;85%
With tin(ll) chloride In water for 5h; Heating;85%
With acetonyltriphenylphosphonium bromide In methanol; dichloromethane at 20℃; for 0.166667h;83%
5-hydroxymethyl-2-furfuraldehyde
67-47-0

5-hydroxymethyl-2-furfuraldehyde

(2-furyl)methyl alcohol
98-00-0

(2-furyl)methyl alcohol

Conditions
ConditionsYield
With palladium nanoparticles deposited on porous SBA-15 In cyclohexane at 130℃; for 12h; Reagent/catalyst; Temperature; Solvent; Time; Molecular sieve;96%
With palladium/alumina In hexane at 145℃; under 45004.5 Torr; for 4h; Catalytic behavior; Reagent/catalyst; Green chemistry;95.6%
With zirconium hydroxide; ethanol at 150℃; Flow reactor;84%
C13H21BO2

C13H21BO2

(2-furyl)methyl alcohol
98-00-0

(2-furyl)methyl alcohol

Conditions
ConditionsYield
With sodium hydroxide In water Inert atmosphere;95%
furfural
98-01-1

furfural

A

(2-furyl)methyl alcohol
98-00-0

(2-furyl)methyl alcohol

B

1,2-di-furan-2-yl-ethane-1,2-diol
4464-77-1, 69314-24-5, 69314-25-6, 116204-42-3

1,2-di-furan-2-yl-ethane-1,2-diol

Conditions
ConditionsYield
With potassium hydroxide at 20℃; under 760.051 Torr; Reagent/catalyst; Electrochemical reaction; Green chemistry;A n/a
B 94%
With sodium hydroxide; aluminium In methanol; water for 0.166667h; pinacol coupling; microwave irradiation;A 10%
B 70%
With acetic acid; zinc In water at 20℃; for 0.333333h; Green chemistry;A 39%
B 51%
With naphthalene; lithium; manganese(ll) chloride In tetrahydrofuran at 50 - 54℃; for 1h; sonication;A 12%
B 37%
With manganese; 2,4,6-collidine hydrochloride In tetrahydrofuran; water at 27℃; for 24h; Inert atmosphere; Schlenk technique; Overall yield = 95 %; Overall yield = 92 mg; chemoselective reaction;
Conditions
ConditionsYield
In further solvent(s) argon-filled glovebox, durene, bibenzyl, heating 6h;A 59%
B 94%
C 1%
D 5%
2-(furan-2-ylmethoxy)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

2-(furan-2-ylmethoxy)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

(2-furyl)methyl alcohol
98-00-0

(2-furyl)methyl alcohol

Conditions
ConditionsYield
With silica gel In ethyl acetate; Petroleum ether94%
With water; silica gel In methanol at 60℃; Inert atmosphere;88%
In methanol at 20℃; for 6h; Inert atmosphere; Glovebox;74%
5-hydroxymethyl-2-furfuraldehyde
67-47-0

5-hydroxymethyl-2-furfuraldehyde

A

2-methylfuran
534-22-5

2-methylfuran

B

(2-furyl)methyl alcohol
98-00-0

(2-furyl)methyl alcohol

C

2,5-dimethylfuran
625-86-5

2,5-dimethylfuran

Conditions
ConditionsYield
With hydrogen In 1,4-dioxane at 180℃; under 11251.1 Torr; for 2h; Catalytic behavior;A n/a
B n/a
C 93.4%
(furan-2-ylmethoxy)trimethylsilane
2846-62-0

(furan-2-ylmethoxy)trimethylsilane

(2-furyl)methyl alcohol
98-00-0

(2-furyl)methyl alcohol

Conditions
ConditionsYield
With 1,4-diazabicyclo[2.2.2]octane tribromide supported on magnetic Fe3O4 nanoparticles In methanol at 20℃; for 0.0833333h;93%
With water; boric acid at 20℃; for 1h;87%
With aminosulfonic acid; water at 20℃; for 2h;85%
furfural
98-01-1

furfural

cyclohexylamine
108-91-8

cyclohexylamine

A

(2-furyl)methyl alcohol
98-00-0

(2-furyl)methyl alcohol

B

N-cyclohexan-1-(furan-2-yl)methanamine
4439-54-7

N-cyclohexan-1-(furan-2-yl)methanamine

C

N-(furan-2-ylmethylene)cyclohexanamine
69819-61-0

N-(furan-2-ylmethylene)cyclohexanamine

D

N-((tetrahydrofuran-2-yl)methyl)cyclohexanamine

N-((tetrahydrofuran-2-yl)methyl)cyclohexanamine

Conditions
ConditionsYield
With hydrogen; Pd on polytris(hydroxymethyl)melamine In ethanol at 45℃; under 757.6 Torr; for 1h; Rate constant; Kinetics; activation energy, other catalysts: Pd/C, palladium on aminated and chloromethylated styrene-divinylbenzene copolymer anion exchange resin AV-17-8 matrix, other solvents: 1-propanol, 2-propanol, 1-butanol, 2-methyl-2-propanol, toluene, hexane;A n/a
B n/a
C n/a
D 92%
5-bromo-2-furancarboxaldehyde
1899-24-7

5-bromo-2-furancarboxaldehyde

A

(2-furyl)methyl alcohol
98-00-0

(2-furyl)methyl alcohol

B

(5-bromo-2-furan-2-yl)methanol
27230-58-6

(5-bromo-2-furan-2-yl)methanol

Conditions
ConditionsYield
With lithium aluminium tetrahydride In diethyl ether at 0℃; for 2h;A 9%
B 91%
5-hydroxymethyl-2-furfuraldehyde
67-47-0

5-hydroxymethyl-2-furfuraldehyde

A

(2-furyl)methyl alcohol
98-00-0

(2-furyl)methyl alcohol

B

2,5-diformylfurane
823-82-5

2,5-diformylfurane

Conditions
ConditionsYield
With carbon dioxide; palladium/alumina In tetrahydrofuran at 145℃; under 45004.5 Torr; for 4h; Catalytic behavior; Reagent/catalyst; Green chemistry;A 90.9%
B 5.5%
With Pd/γ-Al2O3 In 1,4-dioxane at 160℃; for 16h; Inert atmosphere; Autoclave;
furfural
98-01-1

furfural

A

Tetrahydrofurfuryl alcohol
97-99-4

Tetrahydrofurfuryl alcohol

B

(2-furyl)methyl alcohol
98-00-0

(2-furyl)methyl alcohol

Conditions
ConditionsYield
With hydrogen at 90℃; under 15001.5 Torr; Reagent/catalyst;A 90.5%
B 8.4%
With hydrogen In butan-1-ol at 40℃; under 30003 Torr; for 7h; Catalytic behavior; Reagent/catalyst;A 12%
B 85%
With hydrogen In tetrahydrofuran at 175℃; under 7500.75 Torr; for 8h; Catalytic behavior; Pressure; Temperature; Time; chemoselective reaction;A 10%
B 79.5%
D-xylose
58-86-6

D-xylose

(2-furyl)methyl alcohol
98-00-0

(2-furyl)methyl alcohol

Conditions
ConditionsYield
With dodecatungstosilic acid; formic acid In tert-butyl alcohol for 3h; Kinetics; Activation energy; Reagent/catalyst; chemoselective reaction;90.1%
Multi-step reaction with 2 steps
1.1: formic acid / tetrahydrofuran; dimethyl sulfoxide / 150 °C
2.1: Cp*Ir(TsDPEN); triethylamine / tetrahydrofuran; dimethyl sulfoxide / 0.08 h / 40 °C
2.2: 40 °C
View Scheme
Multi-step reaction with 2 steps
1: sodium chloride; aluminum (III) chloride / iso-butanol / 140 °C / Autoclave
2: isopropyl alcohol; iron oxide / 5 h / 160 °C / Autoclave
View Scheme
furfural
98-01-1

furfural

isopropyl alcohol
67-63-0

isopropyl alcohol

A

(2-furyl)methyl alcohol
98-00-0

(2-furyl)methyl alcohol

B

4-(furan-2-yl)but-3-en-2-one
623-15-4

4-(furan-2-yl)but-3-en-2-one

C

isopropopyl (2-methylfuran) ether
113984-01-3

isopropopyl (2-methylfuran) ether

Conditions
ConditionsYield
With iron oxide at 160℃; for 5h; Reagent/catalyst; Temperature; Autoclave;A 90.1%
B n/a
C n/a
at 219.84℃; under 760.051 Torr; Temperature; Flow reactor; Inert atmosphere;
With 2 wt% MgO loaded on amorphous silica at 159.84℃; under 3750.38 Torr; for 12h; Reagent/catalyst; Inert atmosphere;A 9.2 %Chromat.
B 9.2 %Chromat.
C 14.2 %Chromat.
2-furanoic acid
88-14-2

2-furanoic acid

(2-furyl)methyl alcohol
98-00-0

(2-furyl)methyl alcohol

Conditions
ConditionsYield
With strain of the zygomycete fungus S. racemosum MUT 770 In dimethyl sulfoxide for 72h; Enzymatic reaction;90%
Stage #1: 2-furanoic acid With trimethylphenylsilane; C69H55ClP3Ru In tetrahydrofuran at 60℃; for 16h; Glovebox;
Stage #2: With hydrogenchloride In tetrahydrofuran; water at 20℃; for 1h; Glovebox; chemoselective reaction;
65%
With sodium tetrahydroborate; N,N-dimethylchloromethyleniminium chloride 1.) acetonitrile, THF, 0 deg C, 1 h; 2.) acetonitrile, THF, N,N-dimethylformamide, -78 deg C to -20 deg C, 2 h; Yield given. Multistep reaction;
furfurylacetate
623-17-6

furfurylacetate

(2-furyl)methyl alcohol
98-00-0

(2-furyl)methyl alcohol

Conditions
ConditionsYield
With lipase B from Candida antarctica immobilized on Immobead 150 In aq. phosphate buffer at 40℃; for 0.333333h; pH=7.4;89%
With methanol; potassium permanganate; trimethylsulphonium iodide at 25℃; under 760.051 Torr; chemoselective reaction;80%
With methanol; potassium permanganate at 25℃; chemoselective reaction;78%
With [t-Bu2SnOH(Cl)]2 In methanol at 30℃; for 24h; Deacetylation;82 % Chromat.
[t-Bu2SnOH(Cl)]2 In methanol at 30℃; for 24h;82 % Chromat.
(furan-2-yl)methylene diacetate
613-75-2

(furan-2-yl)methylene diacetate

(2-furyl)methyl alcohol
98-00-0

(2-furyl)methyl alcohol

Conditions
ConditionsYield
With sodium tetrahydroborate; nickel(II) chloride hexahydrate In methanol at 20℃; for 4h; chemoselective reaction;86%
furan-3-carboxaldehyde
498-60-2

furan-3-carboxaldehyde

(2-furyl)methyl alcohol
98-00-0

(2-furyl)methyl alcohol

Conditions
ConditionsYield
With C22H21ClN3RuS2(1+)*F6P(1-); isopropyl alcohol; potassium hydroxide In acetonitrile at 80℃; for 3h; Catalytic behavior; Concentration; Reagent/catalyst;85%
C11H12O2Si

C11H12O2Si

(2-furyl)methyl alcohol
98-00-0

(2-furyl)methyl alcohol

Conditions
ConditionsYield
With sodium hydroxide In water Schlenk technique; Inert atmosphere;85%
With sodium hydroxide In water
furfural
98-01-1

furfural

A

2-methylfuran
534-22-5

2-methylfuran

B

(2-furyl)methyl alcohol
98-00-0

(2-furyl)methyl alcohol

Conditions
ConditionsYield
With hydrogen at 160℃; under 760.051 Torr; for 24h; Reagent/catalyst; Temperature;A n/a
B 84.7%
With hydrogen; CuO on Al2O3 at 250℃; Product distribution; gas phase, flow reactor, oth. temperature, var. ratio of reactants;A 69.7%
B 4.2%
With hydrogen In isopropyl alcohol at 200℃; under 22502.3 Torr; Autoclave;A 66%
B 6%
S-phenyl furan-2-carbothioate
17357-38-9

S-phenyl furan-2-carbothioate

(2-furyl)methyl alcohol
98-00-0

(2-furyl)methyl alcohol

Conditions
ConditionsYield
With zinc(II) tetrahydroborate In tetrahydrofuran; diethyl ether for 96h; Ambient temperature;84%
(2-furyl)methyl alcohol
98-00-0

(2-furyl)methyl alcohol

Tetrahydrofurfuryl alcohol
97-99-4

Tetrahydrofurfuryl alcohol

Conditions
ConditionsYield
With 3% Pd/C; hydrogen In isopropyl alcohol at 219.84℃; under 25858.1 Torr; for 5h; Inert atmosphere;100%
With hydrogen In isopropyl alcohol at 25℃; under 7500.75 Torr; for 3h; Green chemistry;100%
With palladium on activated charcoal; ammonia; hydrogen In tetrahydrofuran at 160℃; for 4h; Reagent/catalyst; Autoclave;100%
(2-furyl)methyl alcohol
98-00-0

(2-furyl)methyl alcohol

tert-butyldimethylsilyl chloride
18162-48-6

tert-butyldimethylsilyl chloride

tert-butyl(furan-2-ylmethoxy)dimethylsilane
121389-55-7

tert-butyl(furan-2-ylmethoxy)dimethylsilane

Conditions
ConditionsYield
With dmap; triethylamine In dichloromethane at -78 - 20℃;100%
With 1H-imidazole In N,N-dimethyl-formamide99%
With 1H-imidazole In N,N-dimethyl-formamide at 23℃; for 0.5h;97%
(2-furyl)methyl alcohol
98-00-0

(2-furyl)methyl alcohol

propargyl bromide
106-96-7

propargyl bromide

2-((prop-2-yn-1-yloxy)methyl)furan
32904-79-3

2-((prop-2-yn-1-yloxy)methyl)furan

Conditions
ConditionsYield
Stage #1: (2-furyl)methyl alcohol With sodium hydride In N,N-dimethyl-formamide at 0℃; for 1.5h;
Stage #2: propargyl bromide In N,N-dimethyl-formamide at 20℃; Reagent/catalyst;
100%
With para-chlorotoluene; lithium In tetrahydrofuran at -35 - 20℃; for 10h; Heating / reflux;93%
Stage #1: (2-furyl)methyl alcohol With sodium hydride In N,N-dimethyl-formamide at 0℃; for 0.166667h;
Stage #2: propargyl bromide In N,N-dimethyl-formamide; toluene at 23℃; for 4h;
86%
(2-furyl)methyl alcohol
98-00-0

(2-furyl)methyl alcohol

furfural
98-01-1

furfural

Conditions
ConditionsYield
With bis(2,2'-bipyridyl) copper(II) permanganate In acetone for 0.1h; Ambient temperature;100%
With 4 A molecular sieve; tetrabutylammonium perchlorate; Ru-Cu-Al-hydrotalcite In toluene at 60℃; for 3h;100%
With potassium carbonate In toluene at 70℃; for 2.5h; Reagent/catalyst;100%
(2-furyl)methyl alcohol
98-00-0

(2-furyl)methyl alcohol

2-chloro-4-methoxypyrimidine
22536-63-6

2-chloro-4-methoxypyrimidine

2-(Furan-2-ylmethoxy)-4-methoxy-pyrimidine

2-(Furan-2-ylmethoxy)-4-methoxy-pyrimidine

Conditions
ConditionsYield
With sodium alkoxide100%
(2-furyl)methyl alcohol
98-00-0

(2-furyl)methyl alcohol

potassium 4-(methoxy)phenyltrifluoroborate

potassium 4-(methoxy)phenyltrifluoroborate

2-(4-methoxyphenoxymethyl) furan

2-(4-methoxyphenoxymethyl) furan

Conditions
ConditionsYield
Stage #1: potassium 4-(methoxy)phenyltrifluoroborate With dmap; copper diacetate; 4 A molecular sieve In dichloromethane at 20℃; for 0.0833333h;
Stage #2: (2-furyl)methyl alcohol With oxygen In dichloromethane at 20℃; for 24h;
100%
(2-furyl)methyl alcohol
98-00-0

(2-furyl)methyl alcohol

2-nitro-N-[2-(tetrahydropyran-2-yloxy)ethyl]benzenesulfonamide
819813-95-1

2-nitro-N-[2-(tetrahydropyran-2-yloxy)ethyl]benzenesulfonamide

N-furfuryl-2-nitro-N-[2-(tetrahydropyran-2-yloxy)ethyl]benzenesulfonamide
819813-96-2

N-furfuryl-2-nitro-N-[2-(tetrahydropyran-2-yloxy)ethyl]benzenesulfonamide

Conditions
ConditionsYield
With triphenylphosphine; diethylazodicarboxylate In toluene at 20℃; for 1h;100%
2-aminopyridine
504-29-0

2-aminopyridine

(2-furyl)methyl alcohol
98-00-0

(2-furyl)methyl alcohol

furan-2-ylmethyl-pyridin-2-yl-amine
46230-01-7

furan-2-ylmethyl-pyridin-2-yl-amine

Conditions
ConditionsYield
With dichloro-[1,3-bis(4-tert-butylbenzyl)perhydrobenzimidazol-2-ylidene](p-cymene)ruthenium(II); potassium tert-butylate at 120℃; for 24h; Reagent/catalyst; Inert atmosphere; Schlenk technique; Sealed tube;100%
With [RuCl(N,N-dimethyl-1-[6-(4'-methylphenyl)pyridin-2-yl]methaneamine(-H))(dppb)]; potassium tert-butylate In tetrahydrofuran; toluene at 110℃; for 24h; Inert atmosphere; Molecular sieve;81%
With C46H45ClN4PRu(1+)*F6P(1-); potassium 2-methylbutan-2-olate In toluene at 150℃; for 18h;77%
(2-furyl)methyl alcohol
98-00-0

(2-furyl)methyl alcohol

aniline
62-53-3

aniline

N-(furan-2-ylmethyl)aniline
4439-56-9

N-(furan-2-ylmethyl)aniline

Conditions
ConditionsYield
With dichloro-[1,3-bis(4-methylbenzyl)perhydrobenzimidazol-2-ylidene](p-cymene)ruthenium(II); potassium tert-butylate at 120℃; for 24h; Reagent/catalyst; Inert atmosphere; Schlenk technique; Sealed tube;100%
With titanium triflimide complex; pyridine ligand In toluene at 100℃; for 2h; Microwave irradiation;98%
With C36H35IrN2P(1+)*C32H12BF24(1-); potassium tert-butylate In diethylene glycol dimethyl ether at 50℃; for 24h; Inert atmosphere;94%
(2-furyl)methyl alcohol
98-00-0

(2-furyl)methyl alcohol

titanium(IV) isopropylate
546-68-9

titanium(IV) isopropylate

C16H24O6Ti
1346523-07-6

C16H24O6Ti

Conditions
ConditionsYield
In cyclohexane Inert atmosphere; Reflux;100%
In cyclohexane for 0.5h; Schlenk technique; Inert atmosphere; Reflux;100%
(2-furyl)methyl alcohol
98-00-0

(2-furyl)methyl alcohol

chloroacetyl chloride
79-04-9

chloroacetyl chloride

(furan-2-yl)methyl 2-chloroacetate
51618-39-4

(furan-2-yl)methyl 2-chloroacetate

Conditions
ConditionsYield
With pyridine In diethyl ether at 0℃;100%
(2-furyl)methyl alcohol
98-00-0

(2-furyl)methyl alcohol

2,4-Xylidine
95-68-1

2,4-Xylidine

C13H15NO

C13H15NO

Conditions
ConditionsYield
With dichloro-[1,3-bis(4-isopropylbenzyl)perhydrobenzimidazol-2-ylidene](p-cymene)ruthenium(II); potassium tert-butylate at 120℃; for 24h; Reagent/catalyst; Inert atmosphere; Schlenk technique; Sealed tube;100%
With dichloro(1‐(2‐vinyloxyethyl)benzimidazole)‐(p‐cymene)ruthenium(II); potassium tert-butylate at 120℃; for 24h; Reagent/catalyst; Schlenk technique; Inert atmosphere;
With [dichloro‑[1,3‑bis(4‑phenylbenzyl)perhydrobenzimidazol‑2‑ylidene](η6-p‑cymene)ruthenium(II)]; potassium tert-butylate In neat (no solvent) at 120℃; for 24h; Reagent/catalyst; Inert atmosphere; Schlenk technique; Sealed tube;100 %Chromat.
With potassium tert-butylate; C46H56Cl2N2Ru In neat (no solvent) at 120℃; for 24h; Reagent/catalyst; Inert atmosphere; Schlenk technique; Sealed tube;76 %Chromat.
(2-furyl)methyl alcohol
98-00-0

(2-furyl)methyl alcohol

4-methyl-2-oxo-2H-chromen-7-yl carbonochloridate

4-methyl-2-oxo-2H-chromen-7-yl carbonochloridate

furan-2-ylmethyl (4-methyl-2-oxo-2H-chromen-7-yl) carbonate

furan-2-ylmethyl (4-methyl-2-oxo-2H-chromen-7-yl) carbonate

Conditions
ConditionsYield
With pyridine In dichloromethane at 0 - 20℃; Inert atmosphere;100%
(2-furyl)methyl alcohol
98-00-0

(2-furyl)methyl alcohol

levulinic acid
123-76-2

levulinic acid

furfuryl levulinate

furfuryl levulinate

Conditions
ConditionsYield
With dmap; dicyclohexyl-carbodiimide In tetrahydrofuran at 20℃; for 3h;100%
(2-furyl)methyl alcohol
98-00-0

(2-furyl)methyl alcohol

methanol
67-56-1

methanol

Nafion-H

Nafion-H

levulinic acid methyl ester
624-45-3

levulinic acid methyl ester

Conditions
ConditionsYield
at 20 - 80℃; for 6h; Temperature; Reagent/catalyst;99.32%
(2-furyl)methyl alcohol
98-00-0

(2-furyl)methyl alcohol

butan-1-ol
71-36-3

butan-1-ol

butyl levulinate
2052-15-5

butyl levulinate

Conditions
ConditionsYield
With 5-sulfosalicylic Acid at 118℃; under 760.051 Torr; for 10h; Catalytic behavior; Temperature;99.3%
With toluene-4-sulfonic acid at 80℃; for 4h; Reagent/catalyst; Temperature; Inert atmosphere;94.2%
With [BmimSO3H]3PW12O40; water at 110℃; for 12h;93%
(2-furyl)methyl alcohol
98-00-0

(2-furyl)methyl alcohol

Dimethoxymethane
109-87-5

Dimethoxymethane

2-((methoxymethoxy)methyl)furan
126825-52-3

2-((methoxymethoxy)methyl)furan

Conditions
ConditionsYield
With Mo(VI)/ZrO2 at 40℃; for 0.333333h; Reagent/catalyst; Reflux; Inert atmosphere; Green chemistry;99.2%
(2-furyl)methyl alcohol
98-00-0

(2-furyl)methyl alcohol

carbon disulfide
75-15-0

carbon disulfide

potassium O-furfuryl dithiocarbonate
89712-86-7

potassium O-furfuryl dithiocarbonate

Conditions
ConditionsYield
With potassium hydroxide In diethyl ether at 20℃; for 12h;99%
With potassium hydroxide In acetone67%
With potassium hydroxide
With potassium hydroxide In tetrahydrofuran at 20℃; under 760.051 Torr;
With potassium hydroxide
(2-furyl)methyl alcohol
98-00-0

(2-furyl)methyl alcohol

acetic anhydride
108-24-7

acetic anhydride

furfurylacetate
623-17-6

furfurylacetate

Conditions
ConditionsYield
With tin(IV) tetraphenylporphyrin perchlorate at 20℃; for 0.0833333h;99%
tetradecafluorohexane at 20℃; for 6h;99%
With [{CpHf(OH2)3}2(μ2-OH)2][OSO2C8F17]4*4H20*2THF at 20℃; for 0.0833333h; chemoselective reaction;98%
(2-furyl)methyl alcohol
98-00-0

(2-furyl)methyl alcohol

2-furanoic acid
88-14-2

2-furanoic acid

Conditions
ConditionsYield
With manganese(IV) oxide; oxygen; sodium hydrogencarbonate In water at 100℃; under 7500.75 Torr; for 24h;99%
With oxygen; 1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazolium chloride; sodium t-butanolate In dichloromethane at 20℃; for 30h; Reagent/catalyst; Molecular sieve;95%
With sodium carbonate In water at 30℃; for 40h; Wavelength; Irradiation;93%
(2-furyl)methyl alcohol
98-00-0

(2-furyl)methyl alcohol

propynoic acid methyl ester
922-67-8

propynoic acid methyl ester

methyl (E)-3-(furan-2-ylmethoxy)acrylate

methyl (E)-3-(furan-2-ylmethoxy)acrylate

Conditions
ConditionsYield
With 1,4-diaza-bicyclo[2.2.2]octane In dichloromethane99%
With tributylphosphine In dichloromethane for 0.0833333h; Ambient temperature;98%
(2-furyl)methyl alcohol
98-00-0

(2-furyl)methyl alcohol

Conditions
ConditionsYield
With sodium hydroxide In water at 240℃; Temperature; Reagent/catalyst; Solvent; Autoclave;99%
With sodium hydroxide In water at 240℃; for 0.02h; Catalytic behavior; Reagent/catalyst; Solvent; Temperature; Autoclave;99%
With sodium hydroxide In water at 240℃; for 0.02h; Reagent/catalyst; Temperature; Solvent; Concentration;99%
(2-furyl)methyl alcohol
98-00-0

(2-furyl)methyl alcohol

1,1,1,3,3,3-hexamethyl-disilazane
999-97-3

1,1,1,3,3,3-hexamethyl-disilazane

(furan-2-ylmethoxy)trimethylsilane
2846-62-0

(furan-2-ylmethoxy)trimethylsilane

Conditions
ConditionsYield
With phenyltrimethylammonium tribromide In dichloromethane at 20℃; for 0.166667h; chemoselective reaction;99%
With lithium perchlorate; silica gel In dichloromethane at 20℃; for 0.0833333h;96%
With Nafion SAC-13 at 20℃; for 0.0833333h;96%
(2-furyl)methyl alcohol
98-00-0

(2-furyl)methyl alcohol

N-phenyltriphenyliminophosphorane
2325-27-1

N-phenyltriphenyliminophosphorane

N-(furan-2-ylmethyl)aniline
4439-56-9

N-(furan-2-ylmethyl)aniline

Conditions
ConditionsYield
With cesium hydroxide; palladium diacetate In toluene at 150℃; for 48h; Aza-Wittig reaction;99%
With 1,1'-bis-(diphenylphosphino)ferrocene; potassium carbonate; bis(1,5-cyclooctadiene)diiridium(I) dichloride In toluene at 110℃; for 24h; indirect aza-Wittig reaction;71%
(2-furyl)methyl alcohol
98-00-0

(2-furyl)methyl alcohol

1,2,3,4-tetrahydro-1,6-dimethyl-2-oxo-4-phenylpyrimidine-5-carboxylic acid
60750-38-1

1,2,3,4-tetrahydro-1,6-dimethyl-2-oxo-4-phenylpyrimidine-5-carboxylic acid

Furfuryl Ester of 1,6-Dimethyl-4-phenyl-2-oxo-1,2,3,4-tetrahydropyrimidine-5-carboxylic Acid
95928-47-5

Furfuryl Ester of 1,6-Dimethyl-4-phenyl-2-oxo-1,2,3,4-tetrahydropyrimidine-5-carboxylic Acid

Conditions
ConditionsYield
With di-isopropyl azodicarboxylate; triphenylphosphine In tetrahydrofuran at 20℃; for 0.00833333h; Mitsunobu esterification;99%

Please post your buying leads,so that our qualified suppliers will soon contact you!

*Required Fields