129249-63-4Relevant academic research and scientific papers
SELECTIVITY IN THE LACTONE FORMATION VIA C-H INSERTION REACTION OF DIAZOMALONATES
Lee, Eun,Jung, Kyung Woon,Kim, Yong Seong
, p. 1023 - 1026 (1990)
Rhodium(II)-acetate mediated intramolecular C-H insertation reactions of alkyl methyl diazomalonates result in the formation of β- and γ-lactones.The selectivity depends on both the substitution pattern of insertion centers and the conformational bias of metallocarbenes.
