Tetrahedron Letters p. 1023 - 1026 (1990)
Update date:2022-07-30
Topics:
Lee, Eun
Jung, Kyung Woon
Kim, Yong Seong
Rhodium(II)-acetate mediated intramolecular C-H insertation reactions of alkyl methyl diazomalonates result in the formation of β- and γ-lactones.The selectivity depends on both the substitution pattern of insertion centers and the conformational bias of metallocarbenes.
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