129265-60-7

Usage

Uses

Used in Analytical Chemistry:
1,10-Phenanthroline, 2,9-bis(4-bromophenyl)is used as a chelating agent for metal ions in analytical chemistry. Its ability to form stable complexes with transition metals allows for the accurate detection and quantification of these metals in various samples.
Used in Biochemistry:
In biochemistry, 1,10-Phenanthroline, 2,9-bis(4-bromophenyl)is used as a fluorescent dye for the detection and analysis of metal ions. Its fluorescence properties enable researchers to study the interactions between metal ions and biomolecules, providing valuable insights into biological processes.
Used in Coordination Chemistry:
1,10-Phenanthroline, 2,9-bis(4-bromophenyl)is used as a ligand in coordination chemistry to form complexes with transition metals. These complexes are essential for understanding the structure, properties, and reactivity of metal-containing compounds.
Used in Catalysis:
In the field of catalysis, 1,10-Phenanthroline, 2,9-bis(4-bromophenyl)is used to form metal complexes that act as catalysts in various chemical reactions. These catalysts play a crucial role in enhancing the efficiency and selectivity of the reactions.
Used in Biological Research:
1,10-Phenanthroline, 2,9-bis(4-bromophenyl)is used as a research tool in biological studies to investigate the role of metal ions in biological systems. Its ability to form stable complexes with transition metals helps researchers understand the mechanisms of metal ion interactions with biomolecules and their impact on cellular processes.
Used in the Development of New Materials and Technologies:
The specific properties of 1,10-Phenanthroline, 2,9-bis(4-bromophenyl)make it a valuable compound for the development of new materials and technologies. Its potential applications include the creation of advanced materials with unique properties, such as improved sensitivity in sensors or enhanced catalytic activity in chemical processes.

Upstream product

• 1190590-49-8 2,9-bis(4-trimethylsilylphenyl)-1,10-phenanthroline 
• 106-37-6 1.4-dibromobenzene 
• 149054-39-7 2-(4'-bromophenyl)-1,10-phenanthroline 
• 5467-74-3 4-Bromophenylboronic acid 
• 207461-15-2 2,9-diiodo-[1,10]phenanthroline 
• 29176-55-4 2,9-dichloro-[1,10]phenanthroline 
• 66-71-7 1,10-Phenanthroline 

Downstream Products

• 129265-61-8 2,9-bis-1,10-phenanthroline 
• 540770-66-9 2,9-bis[4'-(4-pyridyl-4-phenoxy)biphenyl]-1,10-phenanthroline 
• 830328-51-3 C₄₀H₂₈N₂O₄ 
• 1190590-53-4 2,9-bis(4'-(4''-pyridyl)phenyl)-1,10-phenanthroline 
• 120086-02-4 C₁₄₈H₁₅₆N₁₀Zn₂ 
• 129265-63-0 2,9-Bis-(2'-bromomethyl-biphenyl-4-yl)-[1,10]phenanthroline 
• 129265-62-9 {4'-[9-(2'-Hydroxymethyl-biphenyl-4-yl)-[1,10]phenanthrolin-2-yl]-biphenyl-2-yl}-methanol 

Relevant academic research and scientific papers

NOVEL COMPOUND, MATERIAL FOR ORGANIC ELECTROLUMINESCENCE ELEMENT, ORGANIC ELECTROLUMINESCENCE ELEMENT, AND ELECTRONIC DEVICE

A compound is represented by a formula (1) below. In the formula (1), X1 to X8 each independently represent a carbon atom to be bonded to a group represented by a formula (20) below, CRX or a nitrogen atom. At least one of X1 to X8 is a carbon atom to be bonded to the group represented by the formula (2). RX is independently a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 30 carbon atoms, and the like.

NOVEL COMPOUND, MATERIAL FOR ORGANIC ELECTROLUMINESCENCE ELEMENT, ORGANIC ELECTROLUMINESCENCE ELEMENT, AND ELECTRONIC DEVICE

A compound is represented by a formula (1) below. In the formula (1), X 1 to X 8 each independently represent a carbon atom to be bonded to a group represented by a formula (20) below, CR X or a nitrogen atom. At least one of X 1 to X 8 is a carbon atom to be bonded to the group represented by the formula (2). R X is independently a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 30 carbon atoms, and the like.

Phenanthroline ligands with divergent pyridine units

2-Mono- and 2,9-di-substituted 1,10-phenanthrolines with 4-pyridine units attached either via 1,4-phenylene- or 4-ethynyl-phenyl spacers, have been synthesised. The strategy is based on the introduction of 4-trimethylsilylphenyl group(s) at the phenanthro

Quantitative formation of [2]catenanes using copper(I) and palladium(II) as templating and assembling centers: The entwining route and the threading approach

Transition metal-mediated templating and self-assembly have shown powerful potentials for the synthesis of interlocked molecules. These two strategies were combined in designing and preparing a new type of coordination catenanes incorporating Cu(I) and Pd(II) metal centers. The ligand designed here contains a phenanthroline core and pyridine sidearms (compound 1). Using this phenanthroline-pyridine conjugated ligand, two approaches were examined, which were shown to be surprisingly efficient for the catenane synthesis: the entwining route (entwining of two ligands around Cu(I) followed by Pd(II) clipping) and the threading approach (Cu(I)-templated threading of a cyclic ligand on an acyclic ligand followed by the PD(II) clipping of the second ring). In the former method, stepwise treatment of 1 with Cu(CH3CN)4PF6 (templating center) and enPd(NO3)2 (assembling center) gives rise to the quantitative formation of CuPd2 catenane 18. In the latter method, Cu(I) templates the threading of phenanthroline-containing macrocycle 2 on ligand 1, which is followed by Pd(II) clipping to give hetero catenane 20. In both approaches, the formation of catenanes is convincing thanks to the strong templating effect of Cu(I), while the ring closure steps are efficiently furnished by Pd(II)-directed self-assembly.

Synthesis of unsymmetrical 2,8- and 2,9-dihalo-1,10-phenanthrolines and derivatives

A general method for the preparation of the unsymmetrical 2,8- and 2,9- dihalophenanthrolines is presented. The use of these halophenanthrolines as synthetic substrates in the Suzuki and Sonogashira/Castro-Stevens palladium catalyzed chemistry is exemplifed. The derivatized phenanthrolines are seen as key building blocks for the design and construction of topologically complex polynuclear metal coordination complexes.