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2-(4-Bromo-phenyl)-1,10-phenanthroline, also known as 4'-bromo-1,10-phenanthroline, is a chemical compound belonging to the phenanthroline family, characterized by the molecular formula C18H12BrN2. 2-(4-BroMo-phenyl)-1,10-phenanthroline is distinguished by a bromine-substituted phenyl group at the 2-position of the phenanthroline molecule, which endows it with unique chemical properties. It is widely recognized for its applications in coordination chemistry, fluorescence assays, and various scientific fields such as catalysis, material science, and biological studies, including molecular biology and cell imaging.

149054-39-7

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149054-39-7 Usage

Uses

Used in Coordination Chemistry:
2-(4-Bromo-phenyl)-1,10-phenanthroline is utilized as a ligand in coordination complexes with transition metal ions. Its ability to form stable complexes with these metal ions makes it a valuable component in the development of catalysts and materials with tailored properties.
Used in Fluorescence Assays:
Leveraging its fluorescence properties, 2-(4-Bromo-phenyl)-1,10-phenanthroline is employed in fluorescence assays for the detection and quantification of specific analytes. Its fluorescence can be modulated by the presence of target molecules, allowing for sensitive and selective analytical methods.
Used in Material Science:
In the field of material science, 2-(4-Bromo-phenyl)-1,10-phenanthroline contributes to the design and synthesis of new materials with improved or novel properties. Its coordination capabilities with metal ions can lead to the creation of materials with enhanced stability, conductivity, or other desirable characteristics.
Used in Biological Studies:
2-(4-Bromo-phenyl)-1,10-phenanthroline is applied in biological studies as a tool for investigating molecular interactions and cellular processes. Its fluorescence properties make it suitable for use in cell imaging, allowing researchers to visualize and track specific biomolecules or cellular structures.
Used in Molecular Biology:
In molecular biology, 2-(4-Bromo-phenyl)-1,10-phenanthroline is employed for probing the structure and function of biomolecules, such as proteins and nucleic acids. Its ability to interact with these molecules can provide insights into their mechanisms of action and potential applications in biotechnology and medicine.

Check Digit Verification of cas no

The CAS Registry Mumber 149054-39-7 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,4,9,0,5 and 4 respectively; the second part has 2 digits, 3 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 149054-39:
(8*1)+(7*4)+(6*9)+(5*0)+(4*5)+(3*4)+(2*3)+(1*9)=137
137 % 10 = 7
So 149054-39-7 is a valid CAS Registry Number.

149054-39-7SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 17, 2017

Revision Date: Aug 17, 2017

1.Identification

1.1 GHS Product identifier

Product name 2-(4'-bromophenyl)-1,10-phenanthroline

1.2 Other means of identification

Product number -
Other names 2-(4-broMophenyl)-1,10-phenanthroline

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:149054-39-7 SDS

149054-39-7Relevant academic research and scientific papers

HETEROCYCLIC COMPOUND AND ORGANIC LIGHT-EMITTING DEVICE INCLUDING THE SAME

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Paragraph 0400-0402, (2019/02/25)

An organic light-emitting device includes: a first electrode; a second electrode facing the first electrode; and an organic layer between the first electrode and the second electrode, wherein the organic layer comprises an emission layer and a heterocyclic compound of Formula 1: wherein a1 to a3 satisfy a1+a2+a3≥1.

Aromatic amine derivative and organic light-emitting device thereof

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Paragraph 0078; 0079; 0083, (2018/10/19)

The invention provides an aromatic amine derivative and an organic light-emitting device thereof, and relates to the technical field of organic photoelectric materials. The preparation method of the compound is simple, raw materials are easy to obtain, the high hole mobility and Tg and the good stability and film-forming property are achieved, the derivative has the proper highest occupied molecular orbital, and can be adopted as a first hole transmission layer and can also be adopted as a second hole transmission layer. When the derivative is adopted as the first hole transmission layer, theenergy level difference between a light-emitting layer and an anode interface can be lowered; when the derivative is adopted as the second hole transmission layer, the energy level difference betweenthe light-emitting layer and the first hole transmission layer can be lowered, and meanwhile point sum balance inside the light-emitting layer can be achieved. The derivative is applied to an OLED, the light-emitting efficiency and the color purity of the device can be remarkably improved, the service life of the device can be prolonged, the driving voltage of the device can be lowered, and the OLED material is good in performance.

NOVEL COMPOUND, MATERIAL FOR ORGANIC ELECTROLUMINESCENCE ELEMENT, ORGANIC ELECTROLUMINESCENCE ELEMENT, AND ELECTRONIC DEVICE

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Paragraph 0672; 0675; 0676-0678, (2016/10/08)

A compound is represented by a formula (1) below. In the formula (1), X 1 to X 8 each independently represent a carbon atom to be bonded to a group represented by a formula (20) below, CR X or a nitrogen atom. At least one of X 1 to X 8 is a carbon atom to be bonded to the group represented by the formula (2). R X is independently a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 30 carbon atoms, and the like.

NOVEL COMPOUND, MATERIAL FOR ORGANIC ELECTROLUMINESCENCE ELEMENT, ORGANIC ELECTROLUMINESCENCE ELEMENT, AND ELECTRONIC DEVICE

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, (2015/08/03)

A compound is represented by a formula (1) below. In the formula (1), X1 to X8 each independently represent a carbon atom to be bonded to a group represented by a formula (20) below, CRX or a nitrogen atom. At least one of X1 to X8 is a carbon atom to be bonded to the group represented by the formula (2). RX is independently a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 30 carbon atoms, and the like.

BENZO[K]FLUORANTHENE DERIVATIVE AND ORGANIC ELECTROLUMINESCENCE ELEMENT CONTAINING SAME

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Paragraph 0156; 0157, (2013/08/28)

A benzo[k]fluoranthene derivative represented by the following formula (1): wherein R1 to R12 are as defined in the specification. The benzo[k]fluoranthene derivative represented by the formula (1) reduces a driving voltage of an organic electroluminescence device and makes it possible to realize light emission with high efficiency and long lifetime.

Phenanthroline ligands with divergent pyridine units

Vysotsky, Myroslav O.

experimental part, p. 133 - 136 (2009/11/30)

2-Mono- and 2,9-di-substituted 1,10-phenanthrolines with 4-pyridine units attached either via 1,4-phenylene- or 4-ethynyl-phenyl spacers, have been synthesised. The strategy is based on the introduction of 4-trimethylsilylphenyl group(s) at the phenanthro

Quantitative formation of [2]catenanes using copper(I) and palladium(II) as templating and assembling centers: The entwining route and the threading approach

Dietrich-Buchecker, Christiane,Colasson, Benoit,Fujita, Makoto,Hori, Akiko,Geum, Neri,Sakamoto, Shigeru,Yamaguchi, Kentaro,Sauvage, Jean-Pierre

, p. 5717 - 5725 (2007/10/03)

Transition metal-mediated templating and self-assembly have shown powerful potentials for the synthesis of interlocked molecules. These two strategies were combined in designing and preparing a new type of coordination catenanes incorporating Cu(I) and Pd(II) metal centers. The ligand designed here contains a phenanthroline core and pyridine sidearms (compound 1). Using this phenanthroline-pyridine conjugated ligand, two approaches were examined, which were shown to be surprisingly efficient for the catenane synthesis: the entwining route (entwining of two ligands around Cu(I) followed by Pd(II) clipping) and the threading approach (Cu(I)-templated threading of a cyclic ligand on an acyclic ligand followed by the PD(II) clipping of the second ring). In the former method, stepwise treatment of 1 with Cu(CH3CN)4PF6 (templating center) and enPd(NO3)2 (assembling center) gives rise to the quantitative formation of CuPd2 catenane 18. In the latter method, Cu(I) templates the threading of phenanthroline-containing macrocycle 2 on ligand 1, which is followed by Pd(II) clipping to give hetero catenane 20. In both approaches, the formation of catenanes is convincing thanks to the strong templating effect of Cu(I), while the ring closure steps are efficiently furnished by Pd(II)-directed self-assembly.

First synthesis of soluble, well defined coordination polymers from kinetically unstable copper(I) complexes

Velten, Ulf,Rehahn, Matthias

, p. 2639 - 2640 (2007/10/03)

Exclusion of competitive ligands is found to be the central requirement for obtaining solutions of constitutionally homogeneous, high-molecular-mass coordination polymers from kinetically unstable pseudo-tetrahedral complexes of copper(I) and o-phenanthroline derivatives.

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