1292847-89-2Relevant academic research and scientific papers
Copper(II)-catalyzed ortho-benzoxylation of 2-arylpyridines with sodium carboxylates
Li, Liping,Yu, Peng,Cheng, Jiang,Chen, Fan,Pan, Changduo
scheme or table, p. 600 - 602 (2012/08/07)
Copper-catalyzed ortho-benzoxylation of an sp2 CH bond by sodium carboxylates is described. The procedure tolerates carbomethoxy, formyl, bromo, and chloro groups, providing the benzoxylated products in moderate to good yields.
Copper(II)-catalyzed ortho-functionalization of 2-arylpyridines with acyl chlorides
Wang, Wenhui,Pan, Changduo,Chen, Fan,Cheng, Jiang
, p. 3978 - 3980 (2011/05/02)
Copper-catalyzed ortho-benzoxylation of 2-arylpyridine sp2 C-H bonds with acyl chloride is described. Notably, switching the base from t-BuOK to Li2CO3 causes chlorination of the C-H bond to take place. The Royal Society of Chemistry.
