129286-45-9

Upstream product

• 67-56-1 methanol 
• 316137-73-2 C₁₈H₂₁N₃O 
• 1009-14-9 phenyl butyl ketone 
• 149-73-5 trimethyl orthoformate 

Downstream Products

• 4396-98-9 2-phenylhexan-2-ol 
• 139132-61-9 (S)-2-((2R,4S)-2-Butyl-2-phenyl-[1,3]dioxolan-4-yl)-piperidine 
• 139132-61-9 (S)-2-((2S,4S)-2-Butyl-2-phenyl-[1,3]dioxolan-4-yl)-piperidine 

Relevant academic research and scientific papers

Practical acetalization and transacetalization of carbonyl compounds catalyzed by recyclable PVP-I

A novel PVP-I catalyzed acetalizations/transacetalizations of carbonyl compounds has been developed processing with a mild and easy handling fashion. Different types of Acyclic and cyclic acetals were prepared from carbonyl compounds or their acetals successfully. Further applications of newly developed catalytic combination were testified. This protocol featured with simplicity of operation, mild reaction condition, short reaction time, recyclable of catalyst and broad substrates scope with excellent yields.

Anodic cleavage of several ketone N-phenylsemicarbazones into methyl N-phenylcarbamate and the corresponding dimethyl acetals

Several ketone N-phenylsemicarbazones were electrooxidized in the presence of potassium iodide and a base using methanol as the solvent to give nearly commensurate amounts of methyl N-phenylcarbamate and the corresponding dimethyl acetals. Continuous evolution of gaseous nitrogen was observed from the anolyte during the electrooxidation. The reactions were carried out under very mild reaction conditions and are presumed to proceed through a four-electron oxidation process, in which the iodide ion plays an important role as an electron carrier.