129476-49-9

Basic information

• Product Name: 1-bromo-4-(dodecylsulfanyl)benzene
• Synonyms: 1-bromo-4-(dodecylsulfanyl)benzene
• CAS NO: 129476-49-9
• Molecular Weight: 357.398
• Mol File: 129476-49-9.mol

Chemical Properties

• CAS DataBase Reference: 1-bromo-4-(dodecylsulfanyl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-bromo-4-(dodecylsulfanyl)benzene(129476-49-9)
• EPA Substance Registry System: 1-bromo-4-(dodecylsulfanyl)benzene(129476-49-9)

Safety Data

• Hazardous Substances Data: 129476-49-9(Hazardous Substances Data)

Upstream product

• 589-87-7 1,4-bromoiodobenzene 
• 112-55-0 1-dodecylthiol 
• 143-15-7 1-dodecylbromide 
• 106-53-6 para-bromobenzenethiol 

Downstream Products

• 1401711-38-3 C₄₁H₆₇NOS₂ 
• 1401711-41-8 (S)-α,α-bis(4-dodecylphenylthio)-2-pyrrolidinemethanol trimethylsilylether 
• 1401711-34-9 C₄₆H₇₅NO₃S₂ 
• 483343-84-6 trifluoro-methanesulfonic acid 4,5-bis-[4-(dodecane-1-sulfonyl)-phenylethynyl]-2-methoxy-phenyl ester 
• 179925-10-1 [4-(Dodecane-1-sulfonyl)-phenylethynyl]-trimethyl-silane 
• 179925-11-2 1-(Dodecane-1-sulfonyl)-4-ethynyl-benzene 
• 179925-09-8 1-bromo-4-(dodecylsulfonyl)benzene 

Relevant articles and documents

Microwave-Assisted Copper-Catalyzed Cross-Coupling Reaction of Thiols with Aryl Iodides in Water

Microwave-promoted C-S bond formation from thiols and aryl iodides in the presence of a copper catalyst is reported. A combination of copper(II) oxide and 1,10-phenanthroline catalyzes this reaction. A variety of aryl iodides react smoothly with thiols to provide the corresponding aryl sulfides in good to excellent yields. Notably, the reactions proceed in water with a short reaction time (30 minutes). This system shows broad functional-group tolerance; amino, chloro, bromo, acetyl, and nitro groups are unaffected by the reaction conditions.

An eco-friendly asymmetric organocatalytic conjugate addition of malonates to α,β-unsaturated aldehydes: Application on the synthesis of chiral indoles

The asymmetric Michael addition of malonates to α,β-unsaturated aldehydes using a modified Jorgensen-Hayashi organocatalyst in EtOH:brine solvent media is reported. The procedure proceeds smoothly to afford the corresponding Michael adducts in good yields with excellent enantioselectivities. The resulting Michael adducts represent excellent building blocks for the synthesis of chiral indoles. The asymmetric Michael reaction using a modified Jorgensen-Hayashi organocatalyst in EtOH:brine solvent media is reported. This procedure afforded the corresponding Michael adducts in good yields and with excellent enantioselectivities. The resulting adducts were further used as chiral building blocks for the synthesis of indoles. Copyright

A general rhodium-catalyzed cross-coupling reaction of thiols with aryl iodides

The general procedure for the rhodium-catalyzed cross-coupling of thiols with aryl iodides is described. The catalytic system consists of 5 mol % of [RhCl(cod)]2 and 10 mol % of PPh3 as a ligand. A variety of aryl iodides reacted with thiols, giving aryl thioethers in good to excellent yields. It is important to note that the deactivated aryl iodides such as 4-iodoanisole is worked smoothly to provide the corresponding aryl thioethers in excellent yields. Functional groups such as free-amines, chloro, are all tolerated under the employed reaction conditions.

Recyclable heterogeneous supported copper-catalyzed coupling of thiols with aryl halides: base-controlled differential arylthiolation of bromoiodobenzenes

Alumina-supported copper sulfate efficiently catalyzes the 5-arylation of aromatic, heteroaromatic and aliphatic thiols with aryl as well as heteroaryl halides under aerobic, ligand-free conditions. This protocol provides an easy access to a variety of thioethers as well as unsymmetrical bis-thioethers by base-controlled differential coupling of thiols with iodo- and bromo-substituents in an aromatic halide. The catalyst is inexpensive, non-air sensitive, environmentally friendly and recyclable.

Soluble dipolar dendrimers with peripheral sulfone groups

A dipolar dendron based on meta and para linked poly(phenyl acetylene)s with eight electron donor-acceptor pairs in direct conjugations is synthesized through a convergent approach.

Enhanced Aggreagtion of Derivatized Tolan Surfactants through Donor-Acceptor Interactions at the Air-Water Interface and in Langmuir-Blodgett Films

Control of aggregation behavior of derivatized surfactants by moderately polar functional groups as well as the role of charge-transfer interactions governing photophysical phenomena was studied using surfactants incorporating the diphenylacetylene (tolan