129540-75-6Relevant academic research and scientific papers
Prescursors for and synthesis of mono- and difunctionalized acetylenes and difunctional 1,3-diynes
-
, (2008/06/13)
Precursors and methods for the synthesis of mono- and difunctionalized acetylenes are described. The invention includes novel tricoordinate iodonium transfer reagents and novel alkynyldi(phenyliodonium) salts, both of which are precursors for the function
A General Approach to Aryl(cyano)iodonium Triflates - Versatile Iodonium Transfer Reagents
Zhdankin, Viktor V.,Scheuller, Michael C.,Stang, Peter J.
, p. 6853 - 6856 (2007/10/02)
Aryl(cyano)iodonium triflates (ArI+CN -OTf, Ar = Ph, 4-CF3C6H4, 3,5-(CF3)2C6H3, 4-FC6H4) can be prepared in two steps from the corresponding aryliodides by oxidation with pertrifluoroacetic acid and subsequent reaction with Me3SiOTf
